Multilayered La0.7Ce0.3Fe11.6Si1.4/Fe composites and their hydrides for magnetic refrigeration near room temperature

Chunhui Li, Mingxiao Zhang*, Hangcheng Li, Zhiyang Wei, Zhenxing Li, Yunbo Zhong, Jian Liu, Aru Yan

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

摘要

Magnetocaloric composites with alternately stacked Fe layers and porous La0.7Ce0.3Fe11.6Si1.4 layers were prepared by powder metallurgy. Such a multilayered structure allows the composites to transfer heat faster in the parallel direction to Fe layers than the perpendicular one and maintain a mechanical stability during hydrogenation. Thermal conductivity differences between the two directions at 300 K are 4.1 W/m K for the La0.7Ce0.3Fe11.6Si1.4/Fe composites and 2.0 W/m K for their hydrides. The hydrides exhibit a large entropy change of 12.3 J/kg K and a temperature change of 2.1 K under a low magnetic field change of 1 T near 316 K. Besides, the temperature change of the hydrides remains almost constant during 10,000 continuous magnetic cycles. The highly anisotropic thermal conductivity, large magnetocaloric effect and good fatigue resistance make these multilayered composites potential candidates for the application as high-performance magnetic refrigerants.

源语言英语
文章编号178415
期刊Journal of Alloys and Compounds
1013
DOI
出版状态已出版 - 31 1月 2025

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引用此

Li, C., Zhang, M., Li, H., Wei, Z., Li, Z., Zhong, Y., Liu, J., & Yan, A. (2025). Multilayered La0.7Ce0.3Fe11.6Si1.4/Fe composites and their hydrides for magnetic refrigeration near room temperature. Journal of Alloys and Compounds, 1013, 文章 178415. https://doi.org/10.1016/j.jallcom.2024.178415