Multielement Flame-Retardant System Constructed with Metal POSS-Organic Frameworks for Epoxy Resin

Boyou Hou, Wenyuan Zhang, Hongyu Lu, Kunpeng Song, Zhishuai Geng, Xinming Ye, Ye Tang Pan*, Wenchao Zhang*, Rongjie Yang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

36 引用 (Scopus)

摘要

The direct coordination between polyhedral oligomeric silsesquioxane (POSS) and Co forms an assembly of nanoparticles with low specific surface area and leads to a poor dispersion state in the epoxy resin matrix, resulting in unsatisfactory flame-retardant efficiency. Metal-organic frameworks (MOFs), for instance, ZIF-67, provide not only the cobalt element but also the porous framework that endows the nanocomposite of MOFs and POSS with high specific surface area and abundant Co sites in the silica skeleton. Herein, ZIF-67 is hybridized with octacarboxyl POSS, resulting in the removal of the alkaline ligand to form novel metal POSS-organic frameworks (MPOFs). The size differences for organic groups and silica nanocages of POSS vs. micropores of ZIF-67 gave rise to a reverse click reaction, reforming octavinyl POSS isolated on the outer surface of the Co complex, which could be further modified by a phosphorous flame retardant using an addition reaction. The obtained MPOFs-P with 2 wt % loading in epoxy resin could improve the limiting oxygen index value of the composites to 27.0% and pass the V-0 rating in the UL-94 test. Meanwhile, the peaks of the heat release rate and especially the total smoke production were reduced by 46.6 and 25.2%, respectively. The robust char layer reduces the emission of toxic gas CO by 39.8%. The above epoxy product with promising flame retardancy also improved mechanical properties, thanks to the filler with a unique nanostructure. The ingenious work offers enlightenment for the hybridization method of MOFs and POSS to fabricate a multielement flame-retardant system for epoxy resin with high efficacy.

源语言英语
页(从-至)49326-49337
页数12
期刊ACS applied materials & interfaces
14
43
DOI
出版状态已出版 - 2 11月 2022

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