Metalloporphyrin-based supramolecular catalysts

Yang Zaiwen*, Yang Jin, Huang Xiaojuan, Tang Ning, Wu Biao

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

1 引用 (Scopus)

摘要

Metalloporphyrin-based supramolecular catalyst is one of the most important research subjects in supramolecular catalysis. Supramolecular micro-reactors containing the metalloporphyrin backbone provide a specific micro-environment for the active sites in catalytic processes, which can greatly improve the selectivities and catalytic efficiencies of the catalysts. This review presents the recent progress in the design, structures and catalytic properties of metalloporphyrins as supramolecular catalysts from the aspects of the construction of supramolecular catalyst precursors (based on cyclodextrin, template, etc.) and their catalytic applications (in mimicking cytochrome P450 enzymes, electrocatalysis, photocatalysis, etc. ) , as well as a perspective of the future development in this field.

源语言英语
页(从-至)588-599
页数12
期刊Progress in Chemistry
21
4
出版状态已出版 - 4月 2009
已对外发布

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Zaiwen, Y., Jin, Y., Xiaojuan, H., Ning, T., & Biao, W. (2009). Metalloporphyrin-based supramolecular catalysts. Progress in Chemistry, 21(4), 588-599.