摘要
A biscyclometalated ruthenium complex bridged by the 2,7-deprotonated form of 1,3,6,8-tetra(2-pyridyl)pyrene was deposited onto indium-tin oxide glass electrodes by reductive electropolymerization. The resulting metallopolymeric films exhibited tricolor electrochromic behavior in the near-infrared region upon switching of the two well-separated Ru II/III processes at low potentials. A good contrast ratio (35%) at 2050 nm and a long memory time up to 100 min were recorded for this electrochromic behavior. The response time is typically of a few seconds.
| 源语言 | 英语 |
|---|---|
| 页（从-至） | 6259-6263 |
| 页数 | 5 |
| 期刊 | Inorganic Chemistry |
| 卷 | 51 |
| 期 | 11 |
| DOI | |
| 出版状态 | 已出版 - 4 6月 2012 |
| 已对外发布 | 是 |
指纹
探究 'Metallopolymeric films based on a biscyclometalated ruthenium complex bridged by 1,3,6,8-tetra(2-pyridyl)pyrene: Applications in near-infrared electrochromic windows' 的科研主题。它们共同构成独一无二的指纹。引用此
Yao, C. J., Yao, J., & Zhong, Y. W. (2012). Metallopolymeric films based on a biscyclometalated ruthenium complex bridged by 1,3,6,8-tetra(2-pyridyl)pyrene: Applications in near-infrared electrochromic windows. Inorganic Chemistry, 51(11), 6259-6263. https://doi.org/10.1021/ic3004646