TY - JOUR
T1 - Linear oxalato- and 4,4′-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis
AU - Wu, Ben Lai
AU - Xu, Yan Qing
AU - Gong, Ya Qiong
AU - Huang, You Gui
AU - Hong, Mao Chun
PY - 2007/12
Y1 - 2007/12
N2 - The reaction of 1,3-bis(pyridyl-4-ylthio)propan-2-one with Cu(ClO4)2·6H2O gave a new complex {[Cu2(4PDS)2(ox)(H2O)4](ClO4)2}n (4PDS = 4,4′-dipyridyldisulfide, ox = oxalate), with 4PDS and ox being created by the Cu(II)-assisted oxidation of 1,3-bis(pyridyl-4-ylthio)propan-2-one. The complex determined by X-ray crystallography is a 1D polymer, in which metallacycles formed by two 4PDS and two Cu(II) ions are further bridged through ox anions. It crystallizes in the orthorhombic system, space group Fddd, with lattice parameters a = 15.106(2), b = 23.667(4), c = 27.637(3) Å and Z = 8.
AB - The reaction of 1,3-bis(pyridyl-4-ylthio)propan-2-one with Cu(ClO4)2·6H2O gave a new complex {[Cu2(4PDS)2(ox)(H2O)4](ClO4)2}n (4PDS = 4,4′-dipyridyldisulfide, ox = oxalate), with 4PDS and ox being created by the Cu(II)-assisted oxidation of 1,3-bis(pyridyl-4-ylthio)propan-2-one. The complex determined by X-ray crystallography is a 1D polymer, in which metallacycles formed by two 4PDS and two Cu(II) ions are further bridged through ox anions. It crystallizes in the orthorhombic system, space group Fddd, with lattice parameters a = 15.106(2), b = 23.667(4), c = 27.637(3) Å and Z = 8.
KW - Copper(II) complex
KW - Single crystal structure
KW - Situ ligand synthesis
UR - http://www.scopus.com/inward/record.url?scp=35348818668&partnerID=8YFLogxK
U2 - 10.1080/00958970701278240
DO - 10.1080/00958970701278240
M3 - Article
AN - SCOPUS:35348818668
SN - 0095-8972
VL - 60
SP - 2527
EP - 2532
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 23
ER -