Li                         2                         Na                         2                         [B                         12                         O                         19                         (OH)                         2                         ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

Bei Bei Han; Jian Wen Cheng; Guo Yu Yang

doi:10.1039/c8ce02175a

Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

Bei Bei Han, Jian Wen Cheng^*, Guo Yu Yang

^*此作品的通讯作者

化学与化工学院

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7 引用（Scopus）

摘要

The solvothermal reaction of H ₃ BO ₃ , Li ₂ B ₄ O ₇ , Na ₂ B ₄ O ₇ ·10H ₂ O, 1,2-diaminopropane and pyridine led to a new open framework borate, Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ] (1). Compound 1 crystallizes in the monoclinic space group C2/c. Its structure contains a large cyclic [B ₁₂ O ₂₂ (OH) ₂ ] ¹⁰⁻ cluster, which is connected to six neighboring ones via corner-sharing O atoms to give a 6-connected pcu network via B-O-B bonds. Notably, large shuttle-like pores are observed along the [001] direction as well as 8-ring channels along the [101] direction, leading to an intersecting channel system. UV/vis diffuse reflectance analysis indicates that the compound has a wide transparency range with a short-wavelength absorption edge below 200 nm.

源语言	英语
页（从-至）	1262-1266
页数	5
期刊	CrystEngComm
卷	21
期	8
DOI	https://doi.org/10.1039/c8ce02175a
出版状态	已出版 - 2019

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10.1039/c8ce02175a

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Han, B. B., Cheng, J. W., & Yang, G. Y. (2019). Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units. CrystEngComm, 21(8), 1262-1266. https://doi.org/10.1039/c8ce02175a

Han, Bei Bei ; Cheng, Jian Wen ; Yang, Guo Yu. / Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ] : a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units. 在: CrystEngComm. 2019 ; 卷 21, 号码 8. 页码 1262-1266.

@article{b51cf3d48ac142d2a2e63d091e35f8ef,

title = "Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units",

abstract = " The solvothermal reaction of H 3 BO 3 , Li 2 B 4 O 7 , Na 2 B 4 O 7 ·10H 2 O, 1,2-diaminopropane and pyridine led to a new open framework borate, Li 2 Na 2 [B 12 O 19 (OH) 2 ] (1). Compound 1 crystallizes in the monoclinic space group C2/c. Its structure contains a large cyclic [B 12 O 22 (OH) 2 ] 10− cluster, which is connected to six neighboring ones via corner-sharing O atoms to give a 6-connected pcu network via B-O-B bonds. Notably, large shuttle-like pores are observed along the [001] direction as well as 8-ring channels along the [101] direction, leading to an intersecting channel system. UV/vis diffuse reflectance analysis indicates that the compound has a wide transparency range with a short-wavelength absorption edge below 200 nm.",

author = "Han, {Bei Bei} and Cheng, {Jian Wen} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c8ce02175a",

language = "English",

volume = "21",

pages = "1262--1266",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "8",

}

Han, BB, Cheng, JW & Yang, GY 2019, 'Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units', CrystEngComm, 卷 21, 号码 8, 页码 1262-1266. https://doi.org/10.1039/c8ce02175a

Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units. / Han, Bei Bei; Cheng, Jian Wen; Yang, Guo Yu.
在: CrystEngComm, 卷 21, 号码 8, 2019, 页码 1262-1266.

科研成果: 期刊稿件 › 文章 › 同行评审

TY - JOUR

T1 - Li 2 Na 2 [B 12 O 19 (OH) 2 ]

T2 - a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

AU - Han, Bei Bei

AU - Cheng, Jian Wen

AU - Yang, Guo Yu

PY - 2019

Y1 - 2019

N2 - The solvothermal reaction of H 3 BO 3 , Li 2 B 4 O 7 , Na 2 B 4 O 7 ·10H 2 O, 1,2-diaminopropane and pyridine led to a new open framework borate, Li 2 Na 2 [B 12 O 19 (OH) 2 ] (1). Compound 1 crystallizes in the monoclinic space group C2/c. Its structure contains a large cyclic [B 12 O 22 (OH) 2 ] 10− cluster, which is connected to six neighboring ones via corner-sharing O atoms to give a 6-connected pcu network via B-O-B bonds. Notably, large shuttle-like pores are observed along the [001] direction as well as 8-ring channels along the [101] direction, leading to an intersecting channel system. UV/vis diffuse reflectance analysis indicates that the compound has a wide transparency range with a short-wavelength absorption edge below 200 nm.

AB - The solvothermal reaction of H 3 BO 3 , Li 2 B 4 O 7 , Na 2 B 4 O 7 ·10H 2 O, 1,2-diaminopropane and pyridine led to a new open framework borate, Li 2 Na 2 [B 12 O 19 (OH) 2 ] (1). Compound 1 crystallizes in the monoclinic space group C2/c. Its structure contains a large cyclic [B 12 O 22 (OH) 2 ] 10− cluster, which is connected to six neighboring ones via corner-sharing O atoms to give a 6-connected pcu network via B-O-B bonds. Notably, large shuttle-like pores are observed along the [001] direction as well as 8-ring channels along the [101] direction, leading to an intersecting channel system. UV/vis diffuse reflectance analysis indicates that the compound has a wide transparency range with a short-wavelength absorption edge below 200 nm.

UR - http://www.scopus.com/inward/record.url?scp=85061788651&partnerID=8YFLogxK

U2 - 10.1039/c8ce02175a

DO - 10.1039/c8ce02175a

M3 - Article

AN - SCOPUS:85061788651

SN - 1466-8033

VL - 21

SP - 1262

EP - 1266

JO - CrystEngComm

JF - CrystEngComm

IS - 8

ER -

Han BB, Cheng JW, Yang GY. Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units. CrystEngComm. 2019;21(8):1262-1266. doi: 10.1039/c8ce02175a

Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

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Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units