Kinetics of Cd(II) adsorption on strong acid cationic exchange fiber

Mingyu Li*, Zhihao Li, Qingxuan Zeng, Chunbo Liang

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摘要

This paper derived a columnar model to study the kinetics of Cd(II) adsorption on strong acid cationic exchange fiber (SACEF). Mass transfer rate model ion exchange under liquid film control was derived from dynamic adsorption data. The solution of this model was F((t) = 1 - e-Rt; R = 2D(Rć+ Vc)/(r0ćV) in solution with finite volume, while R = 2Dc/(r0ć) in infinite volume. An overall mass transfer coefficient model and its equations were set up under different aqueous concentrations. The simulated results of liquid film control basically correspond to the experimental data, which means it can be used in engineering applications. The value of liquid film diffusive coefficient D was between 10-14 and 10-12 m2·min-1, and the range of was 10-6 to 10-8 m.

源语言英语
页(从-至)29804-29810
页数7
期刊Journal of Physical Chemistry C
118
51
DOI
出版状态已出版 - 26 12月 2014

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Li, M., Li, Z., Zeng, Q., & Liang, C. (2014). Kinetics of Cd(II) adsorption on strong acid cationic exchange fiber. Journal of Physical Chemistry C, 118(51), 29804-29810. https://doi.org/10.1021/jp5083888