KCs2[GaB5O10](OH): A Zeolitic Galloborate Framework with a Nonlinear Optical Property

Wen Fang Liu; Chong An Chen; Xu Yan Li; Guo Yu Yang

doi:10.1021/acs.cgd.3c00049

KCs₂[GaB₅O₁₀](OH): A Zeolitic Galloborate Framework with a Nonlinear Optical Property

Wen Fang Liu, Chong An Chen, Xu Yan Li, Guo Yu Yang^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

An acentric 3D zeolitic galloborate (GBO) KCs₂[GaB₅O₁₀](OH) (1) has been successfully synthesized by a hydrothermal method. The alternation of GaO₄ and B₅O₁₀ clusters constructs the 3D zeolitic framework of 1, exhibiting the unique and topology with different 8-/12-MR and open channels along different directions, which were first observed in zeolitic borates. Second-harmonic generation (SHG) measurements reveal that 1 is a phase-matchable nonlinear optical material with an SHG response of about 1.4 times that of KDP (KH₂PO₄). A UV-vis spectrum shows that 1 has a cutoff edge of 199 nm, indicating its potential applications in deep-UV regions.

源语言	英语
页（从-至）	3556-3561
页数	6
期刊	Crystal Growth and Design
卷	23
期	5
DOI	https://doi.org/10.1021/acs.cgd.3c00049
出版状态	已出版 - 3 5月 2023

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10.1021/acs.cgd.3c00049

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title = "KCs2[GaB5O10](OH): A Zeolitic Galloborate Framework with a Nonlinear Optical Property",

abstract = "An acentric 3D zeolitic galloborate (GBO) KCs2[GaB5O10](OH) (1) has been successfully synthesized by a hydrothermal method. The alternation of GaO4 and B5O10 clusters constructs the 3D zeolitic framework of 1, exhibiting the unique and topology with different 8-/12-MR and open channels along different directions, which were first observed in zeolitic borates. Second-harmonic generation (SHG) measurements reveal that 1 is a phase-matchable nonlinear optical material with an SHG response of about 1.4 times that of KDP (KH2PO4). A UV-vis spectrum shows that 1 has a cutoff edge of 199 nm, indicating its potential applications in deep-UV regions.",

author = "Liu, {Wen Fang} and Chen, {Chong An} and Li, {Xu Yan} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2023 American Chemical Society.",

year = "2023",

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day = "3",

doi = "10.1021/acs.cgd.3c00049",

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AU - Yang, Guo Yu

PY - 2023/5/3

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N2 - An acentric 3D zeolitic galloborate (GBO) KCs2[GaB5O10](OH) (1) has been successfully synthesized by a hydrothermal method. The alternation of GaO4 and B5O10 clusters constructs the 3D zeolitic framework of 1, exhibiting the unique and topology with different 8-/12-MR and open channels along different directions, which were first observed in zeolitic borates. Second-harmonic generation (SHG) measurements reveal that 1 is a phase-matchable nonlinear optical material with an SHG response of about 1.4 times that of KDP (KH2PO4). A UV-vis spectrum shows that 1 has a cutoff edge of 199 nm, indicating its potential applications in deep-UV regions.

AB - An acentric 3D zeolitic galloborate (GBO) KCs2[GaB5O10](OH) (1) has been successfully synthesized by a hydrothermal method. The alternation of GaO4 and B5O10 clusters constructs the 3D zeolitic framework of 1, exhibiting the unique and topology with different 8-/12-MR and open channels along different directions, which were first observed in zeolitic borates. Second-harmonic generation (SHG) measurements reveal that 1 is a phase-matchable nonlinear optical material with an SHG response of about 1.4 times that of KDP (KH2PO4). A UV-vis spectrum shows that 1 has a cutoff edge of 199 nm, indicating its potential applications in deep-UV regions.

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KCs2[GaB5O10](OH): A Zeolitic Galloborate Framework with a Nonlinear Optical Property

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KCs₂[GaB₅O₁₀](OH): A Zeolitic Galloborate Framework with a Nonlinear Optical Property