Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents

Chunlin He; Joseph P. Hooper; Jean'Ne M. Shreeve

doi:10.1021/acs.inorgchem.6b02195

Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents

Chunlin He, Joseph P. Hooper, Jean'Ne M. Shreeve^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

29 引用（Scopus）

摘要

Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO₃^-) or periodate (IO₄^-) anions were synthesized. The synthesis of analogous I₃O₈^- salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared, ¹H nuclear magnetic resonance, and ¹³C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.

源语言	英语
页（从-至）	12844-12850
页数	7
期刊	Inorganic Chemistry
卷	55
期	24
DOI	https://doi.org/10.1021/acs.inorgchem.6b02195
出版状态	已出版 - 19 12月 2016
已对外发布	是

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abstract = "Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO3-) or periodate (IO4-) anions were synthesized. The synthesis of analogous I3O8- salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared, 1H nuclear magnetic resonance, and 13C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.",

author = "Chunlin He and Hooper, {Joseph P.} and Shreeve, {Jean'Ne M.}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

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doi = "10.1021/acs.inorgchem.6b02195",

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T1 - Iodine-Rich Imidazolium Iodate and Periodate Salts

T2 - En Route to Single-Based Biocidal Agents

AU - He, Chunlin

AU - Hooper, Joseph P.

AU - Shreeve, Jean'Ne M.

PY - 2016/12/19

Y1 - 2016/12/19

N2 - Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO3-) or periodate (IO4-) anions were synthesized. The synthesis of analogous I3O8- salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared, 1H nuclear magnetic resonance, and 13C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.

AB - Two classes of iodine-rich salts that consist of iodine-rich cations and iodate (IO3-) or periodate (IO4-) anions were synthesized. The synthesis of analogous I3O8- salts was more difficult because of poor solubility and hydrolytic instability. All iodine-rich salts were fully characterized by infrared, 1H nuclear magnetic resonance, and 13C nuclear magnetic resonance spectroscopy as well as elemental analyses. The molecular structures of compounds 15 and 24 were elucidated by X-ray single-crystal diffraction. Additionally, the heats of formation were calculated with Gaussian 03. The detonation properties and biocidal efficiency were calculated and evaluated using CHEETAH 7.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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Iodine-Rich Imidazolium Iodate and Periodate Salts: En Route to Single-Based Biocidal Agents

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