TY - JOUR
T1 - Iodide-Centered Cuprous Octatomic Ring
T2 - A Luminescent Molecular Thermometer Exhibiting Dual-Emission Character
AU - Yue, Cheng Yang
AU - Liu, Fu Ling
AU - Deng, Wen Ting
AU - Tao, Jun
AU - Hong, Mao Chun
N1 - Publisher Copyright:
© 2017 American Chemical Society.
PY - 2018/1/3
Y1 - 2018/1/3
N2 - Luminescent molecular thermometers have attracted great attention due to their potential application for temperature detection in special environments. By a very simple one-step method, we have synthesized one novel cuprous compound, [I@Cu8(HMTZ)(MTZ)7]·MeCN·2H2O (I@Cu8), which consists of an infrequent octatomic [I@Cu8S8] ring. Importantly, compound I@Cu8 features dual-emitting behavior and shows successive visual luminescent emissions varying from green, to yellow, to orange, and then to red in the temperature range of 80-300 K, suggesting potential application for a luminescent molecular thermometer.
AB - Luminescent molecular thermometers have attracted great attention due to their potential application for temperature detection in special environments. By a very simple one-step method, we have synthesized one novel cuprous compound, [I@Cu8(HMTZ)(MTZ)7]·MeCN·2H2O (I@Cu8), which consists of an infrequent octatomic [I@Cu8S8] ring. Importantly, compound I@Cu8 features dual-emitting behavior and shows successive visual luminescent emissions varying from green, to yellow, to orange, and then to red in the temperature range of 80-300 K, suggesting potential application for a luminescent molecular thermometer.
UR - http://www.scopus.com/inward/record.url?scp=85040171471&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.7b01261
DO - 10.1021/acs.cgd.7b01261
M3 - Article
AN - SCOPUS:85040171471
SN - 1528-7483
VL - 18
SP - 22
EP - 26
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 1
ER -