Insertion reactions of difluorocarbene generated by pyrolysis of hexafluoropropene oxide to O-H bond

Junji Mizukado*, Yasuhisa Matsukawa, Heng Dao Quan, Masanori Tamura, Akira Sekiya

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

8 引用 (Scopus)

摘要

ROCHF2-type fluorinated ethers were synthesized by the reaction of hexafluoropropene oxide (HFPO) with alcohol or phenol. In this reaction, although the insertion reaction of difluorocarbene to OH bond and the nucleophilic attack of alcohol or phenol to HFPO were competition, the insertion reaction proceeded predominantly to give fluorinated ether in the case of low nucleophilic alcohol or phenol. In addition, high reaction pressure is advantageous to the selectivity of the fluorinated ethers in the reaction of HFPO with (CF3)2CHOH or C6F5OH.

源语言英语
页(从-至)365-369
页数5
期刊Journal of Fluorine Chemistry
126
3
DOI
出版状态已出版 - 3月 2005
已对外发布

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