Influence of Extended Conjugation on Photophysical/Electronic Properties and Photoelimination of BN-Heterocycles

Yong Gang Shi, Xiang Wang, Nan Wang, Tai Peng*, Suning Wang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

9 引用 (Scopus)

摘要

A 1,1-hydroboration reaction was used successfully to create brominated BN-heterocyclic compounds, which are amenable to Stille coupling reactions for the construction of new BN-heterocyclic compounds, including a new polymeric BN-heterocycle that has an extended π-conjugated backbone. The conjugated backbone of the new BN-heterocycles was found to have a great influence on the photophysical and electronic properties of this class of compounds. In addition, the photoelimination reactivity of the new BN-heterocycles was also found to be greatly dependent on the extent of the conjugated backbone. Several new 1,2,4-triazole-fused boranaphthalenes have been obtained successfully via photoelimination.

源语言英语
页(从-至)2677-2684
页数8
期刊Organometallics
36
14
DOI
出版状态已出版 - 24 7月 2017

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Shi, Y. G., Wang, X., Wang, N., Peng, T., & Wang, S. (2017). Influence of Extended Conjugation on Photophysical/Electronic Properties and Photoelimination of BN-Heterocycles. Organometallics, 36(14), 2677-2684. https://doi.org/10.1021/acs.organomet.7b00290