Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O

Lirong Zhang; Zhan Shi; Guoyu Yang; Xiaoming Chen; Shouhua Feng

doi:10.1006/jssc.1999.8478

Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)₂]₆[(VO)₁₂O₆B ₁₈O₃₉(OH)₃] · 13H₂O

Lirong Zhang, Zhan Shi, Guoyu Yang, Xiaoming Chen, Shouhua Feng^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

51 引用（Scopus）

摘要

A hydrothermal reaction of NaVO₃, H₃BO₃, Zn(CH₃COO)₂, ethylenediamine, and H₂O gives a coordination cluster [Zn(en)₂]₆[(VO)₁₂O₆B ₁₈O₃₉(OH)₃] · 13H₂O (denoted on Zn₆V₁₂B₁₈). The Zn₆V₁₂B₁₈ crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a = 20.686(3) Å, c = 20.915(4) Å, V = 7751(2) Å³, Z = 3, and R = 0.0689. The structure consists of an 18-membered ring of B₁₈O₃₉(OH)₃ sand-wiched between two alternating edge-sharing vanadium-oxygen clusters V₆O₁₅ by six B-(μ₃-O)-V₂ bonds and three B₂-(μ₃-O)-V bonds. Each of the six zinc atoms coordinated with two ethylenediamine molecules and connected with the B₁₈O₃₉(OH)₃ ring by one Zn-(μ₃-O)-B bond. A water molecule occupied the center of the Zn₆V₁₂B₁₈ cluster. The oxidation states of vanadium in the compound are V(IV) and V(V) in a ratio of 3:1. Other characterizations by IR spectroscopy, TGA, and DTA are also described.

源语言	英语
页（从-至）	450-454
页数	5
期刊	Journal of Solid State Chemistry
卷	148
期	2
DOI	https://doi.org/10.1006/jssc.1999.8478
出版状态	已出版 - 12月 1999
已对外发布	是

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@article{9e1f4028c0144112868e058acbd52584,

title = "Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O",

abstract = "A hydrothermal reaction of NaVO3, H3BO3, Zn(CH3COO)2, ethylenediamine, and H2O gives a coordination cluster [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O (denoted on Zn6V12B18). The Zn6V12B18 crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a = 20.686(3) {\AA}, c = 20.915(4) {\AA}, V = 7751(2) {\AA}3, Z = 3, and R = 0.0689. The structure consists of an 18-membered ring of B18O39(OH)3 sand-wiched between two alternating edge-sharing vanadium-oxygen clusters V6O15 by six B-(μ3-O)-V2 bonds and three B2-(μ3-O)-V bonds. Each of the six zinc atoms coordinated with two ethylenediamine molecules and connected with the B18O39(OH)3 ring by one Zn-(μ3-O)-B bond. A water molecule occupied the center of the Zn6V12B18 cluster. The oxidation states of vanadium in the compound are V(IV) and V(V) in a ratio of 3:1. Other characterizations by IR spectroscopy, TGA, and DTA are also described.",

keywords = "Borate compound, Crystal structure, Hydrothermal synthesis, Polyoxovanadium, Transition metal complex",

author = "Lirong Zhang and Zhan Shi and Guoyu Yang and Xiaoming Chen and Shouhua Feng",

year = "1999",

month = dec,

doi = "10.1006/jssc.1999.8478",

language = "English",

volume = "148",

pages = "450--454",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

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number = "2",

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T1 - Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O

AU - Zhang, Lirong

AU - Shi, Zhan

AU - Yang, Guoyu

AU - Chen, Xiaoming

AU - Feng, Shouhua

PY - 1999/12

Y1 - 1999/12

N2 - A hydrothermal reaction of NaVO3, H3BO3, Zn(CH3COO)2, ethylenediamine, and H2O gives a coordination cluster [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O (denoted on Zn6V12B18). The Zn6V12B18 crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a = 20.686(3) Å, c = 20.915(4) Å, V = 7751(2) Å3, Z = 3, and R = 0.0689. The structure consists of an 18-membered ring of B18O39(OH)3 sand-wiched between two alternating edge-sharing vanadium-oxygen clusters V6O15 by six B-(μ3-O)-V2 bonds and three B2-(μ3-O)-V bonds. Each of the six zinc atoms coordinated with two ethylenediamine molecules and connected with the B18O39(OH)3 ring by one Zn-(μ3-O)-B bond. A water molecule occupied the center of the Zn6V12B18 cluster. The oxidation states of vanadium in the compound are V(IV) and V(V) in a ratio of 3:1. Other characterizations by IR spectroscopy, TGA, and DTA are also described.

AB - A hydrothermal reaction of NaVO3, H3BO3, Zn(CH3COO)2, ethylenediamine, and H2O gives a coordination cluster [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O (denoted on Zn6V12B18). The Zn6V12B18 crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a = 20.686(3) Å, c = 20.915(4) Å, V = 7751(2) Å3, Z = 3, and R = 0.0689. The structure consists of an 18-membered ring of B18O39(OH)3 sand-wiched between two alternating edge-sharing vanadium-oxygen clusters V6O15 by six B-(μ3-O)-V2 bonds and three B2-(μ3-O)-V bonds. Each of the six zinc atoms coordinated with two ethylenediamine molecules and connected with the B18O39(OH)3 ring by one Zn-(μ3-O)-B bond. A water molecule occupied the center of the Zn6V12B18 cluster. The oxidation states of vanadium in the compound are V(IV) and V(V) in a ratio of 3:1. Other characterizations by IR spectroscopy, TGA, and DTA are also described.

KW - Borate compound

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Polyoxovanadium

KW - Transition metal complex

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U2 - 10.1006/jssc.1999.8478

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Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O

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Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)₂]₆[(VO)₁₂O₆B ₁₈O₃₉(OH)₃] · 13H₂O