TY - JOUR
T1 - Hydrothermal synthesis and crystal structure of a new bimetallic oxide cluster constructed from β-octamolybdate and copper (I)-organonitrogen complexes
AU - He, Jiang Hua
AU - Yu, Ji Hong
AU - Pan, Qin He
AU - Chen, Peng
AU - Xu, Ru Ren
PY - 2005/5
Y1 - 2005/5
N2 - A new bimetallic oxide cluster [5-(4-Br-Ph)-2,4'-Hbpy]2[CuI (5-(4-Br-Ph)-2,4'-bpy)2]2 ·[Mo8 O26] (1) was hydrothermally synthesized and structurally solved by single-crystal X-ray diffraction analysis. Crystal data for compound 1: monoclinic, P21/c, a=l.4411(3) nm, b=1.3924(4) nm, c=2.5183(5) nm, β=99.06(3)% V=4.9903(17) nm3, and Z=2. The structure of compound 1 consists of a cluster anion {[CuI (5-(4-Br-Ph)-2,4'-bpy)2]2 [Mo8O26]}2-, which is constructed from β-octamolybdate subunit (Mo8O26)4- covalently bonded to two coordinated complexes {CuI(5-(4-Br-Ph)-2,4'-bpy)2}+. Discrete protonated ligand {5-(4-Br-Ph)-2,4'-Hbpy}+ acts as the charge-compensating cation.
AB - A new bimetallic oxide cluster [5-(4-Br-Ph)-2,4'-Hbpy]2[CuI (5-(4-Br-Ph)-2,4'-bpy)2]2 ·[Mo8 O26] (1) was hydrothermally synthesized and structurally solved by single-crystal X-ray diffraction analysis. Crystal data for compound 1: monoclinic, P21/c, a=l.4411(3) nm, b=1.3924(4) nm, c=2.5183(5) nm, β=99.06(3)% V=4.9903(17) nm3, and Z=2. The structure of compound 1 consists of a cluster anion {[CuI (5-(4-Br-Ph)-2,4'-bpy)2]2 [Mo8O26]}2-, which is constructed from β-octamolybdate subunit (Mo8O26)4- covalently bonded to two coordinated complexes {CuI(5-(4-Br-Ph)-2,4'-bpy)2}+. Discrete protonated ligand {5-(4-Br-Ph)-2,4'-Hbpy}+ acts as the charge-compensating cation.
KW - Crystal structure
KW - Hydrothermal synthesis
KW - Octamolybdate
UR - http://www.scopus.com/inward/record.url?scp=21144438893&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:21144438893
SN - 0251-0790
VL - 26
SP - 797
EP - 800
JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
IS - 5
ER -