Hydrothermal synthesis and crystal structure of a layered vanadium oxide with an interlayer metal co-ordination complex: Cd[C3N2H11]2[V8O 20]

Lirong Zhang, Zhan Shi, Guoyu Yang, Xiaoming Chen, Shouhua Feng*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

104 引用 (Scopus)

摘要

The compound Cd[C3N2H11]2[V8O 20] was synthesized from the hydrothermal reactions of V2O5, CdSO4, 1,2-diaminopropane (enMe) and water in the molar ratio 1:1:2.2:223. Its structure has been determined by single-crystal X-ray diffraction. This compound has an open three-dimensional framework structure consisting of [V8O20]4- layers, composed of equal numbers of VO4 tetrahedra and VO5 pyramids connected by both corner and edge sharing. The Cd[enMeH]24+ complex occupies the interlayer space and connects with the vanadium oxide layers through four Cd-O bonds. This arrangement gives one-dimensional channels with 10-membered rings along the c axis.

源语言英语
页(从-至)275-278
页数4
期刊Journal of the Chemical Society. Dalton Transactions
3
DOI
出版状态已出版 - 2000
已对外发布

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Zhang, L., Shi, Z., Yang, G., Chen, X., & Feng, S. (2000). Hydrothermal synthesis and crystal structure of a layered vanadium oxide with an interlayer metal co-ordination complex: Cd[C3N2H11]2[V8O 20]. Journal of the Chemical Society. Dalton Transactions, (3), 275-278. https://doi.org/10.1039/a908773g