TY - JOUR
T1 - Hydrogen-bond networks of 1,3-imidazolidine-2-thione
T2 - Synthesis and structures of complexes of silver(I), copper(I), cadmium(II) and zinc(II)
AU - Zhu, Qinlei
AU - Chu, Wei
AU - Huang, Rudan
AU - Zhang, Jing
AU - Xu, Yanqing
PY - 2008
Y1 - 2008
N2 - Solution reactions of silver(I), copper(I), cadmium(II) and zinc(II) salts with 1,3-imidazolidine-2-thione (imdt) under diverse conditions yielded four complexes: [Cd(SC3H6N2)2(Ac)2] (1), [Zn(SC3H6N2)2(Ac)2] (2), [Cu2(SC3H6N2)6]SO4 (3) and [Ag2(SC3H6N2)6]SO4 (4). Complexes 1 and 2 are 1D and 2D hydrogen-bond aggregations. Complexes 3 and 4 are isostructural 3D hydrogen-bond networks. The diverse coordination modes of imdt and different anions are the major factors for three distinct hydrogen-bond structures.
AB - Solution reactions of silver(I), copper(I), cadmium(II) and zinc(II) salts with 1,3-imidazolidine-2-thione (imdt) under diverse conditions yielded four complexes: [Cd(SC3H6N2)2(Ac)2] (1), [Zn(SC3H6N2)2(Ac)2] (2), [Cu2(SC3H6N2)6]SO4 (3) and [Ag2(SC3H6N2)6]SO4 (4). Complexes 1 and 2 are 1D and 2D hydrogen-bond aggregations. Complexes 3 and 4 are isostructural 3D hydrogen-bond networks. The diverse coordination modes of imdt and different anions are the major factors for three distinct hydrogen-bond structures.
KW - 1,3-imidazolidine-2-thione
KW - Hydrogen-bond networks
KW - Structure
UR - http://www.scopus.com/inward/record.url?scp=54349121601&partnerID=8YFLogxK
U2 - 10.1080/00958970802051041
DO - 10.1080/00958970802051041
M3 - Article
AN - SCOPUS:54349121601
SN - 0095-8972
VL - 61
SP - 3390
EP - 3400
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 21
ER -