Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

Alexander S. Romanov, Dawei Di, Le Yang, Julio Fernandez-Cestau, Ciaran R. Becker, Charlotte E. James, Bonan Zhu, Mikko Linnolahti*, Dan Credgington, Manfred Bochmann

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

84 引用 (Scopus)

摘要

Linear two-coordinate copper complexes of cyclic (alkyl)(amino)carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4-300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.

源语言英语
页(从-至)6379-6382
页数4
期刊Chemical Communications
52
38
DOI
出版状态已出版 - 2016
已对外发布

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