Highly efficient extraction of sulfate ions with a tripodal hexaurea receptor

Chuandong Jia; Biao Wu; Shaoguang Li; Xiaojuan Huang; Qilong Zhao; Qian Shu Li; Xiao Juan Yang

doi:10.1002/anie.201004461

Highly efficient extraction of sulfate ions with a tripodal hexaurea receptor

Chuandong Jia, Biao Wu^*, Shaoguang Li, Xiaojuan Huang, Qilong Zhao, Qian Shu Li, Xiao Juan Yang

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

172 引用（Scopus）

摘要

Fatal extraction: The Hofmeister bias for sulfate ions in aqueous environments can be overcome by using a tripodal hexaurea receptor (L) that completely encapsulates the sulfate ion in a complementary cavity protected by hydrophobic aromatic rings (see picture; C-gray, N-blue, O-red, S-yellow). Almost quantitative extraction of sulfate ions from an aqueous to an organic phase is achieved when this receptor is used as a liquid-liquid extractant.

源语言	英语
页（从-至）	486-490
页数	5
期刊	Angewandte Chemie - International Edition
卷	50
期	2
DOI	https://doi.org/10.1002/anie.201004461
出版状态	已出版 - 10 1月 2011
已对外发布	是

访问文件

10.1002/anie.201004461

其它文件与链接

链接到 Scopus 的出版物

引用此

Jia, C., Wu, B., Li, S., Huang, X., Zhao, Q., Li, Q. S., & Yang, X. J. (2011). Highly efficient extraction of sulfate ions with a tripodal hexaurea receptor. Angewandte Chemie - International Edition, 50(2), 486-490. https://doi.org/10.1002/anie.201004461

@article{493d8b9ef5574528ab70f461a495c7af,

title = "Highly efficient extraction of sulfate ions with a tripodal hexaurea receptor",

abstract = "Fatal extraction: The Hofmeister bias for sulfate ions in aqueous environments can be overcome by using a tripodal hexaurea receptor (L) that completely encapsulates the sulfate ion in a complementary cavity protected by hydrophobic aromatic rings (see picture; C-gray, N-blue, O-red, S-yellow). Almost quantitative extraction of sulfate ions from an aqueous to an organic phase is achieved when this receptor is used as a liquid-liquid extractant.",

keywords = "anion recognition, chelate effect, host-guest chemistry, hydrophobic effect, receptors",

author = "Chuandong Jia and Biao Wu and Shaoguang Li and Xiaojuan Huang and Qilong Zhao and Li, {Qian Shu} and Yang, {Xiao Juan}",

year = "2011",

month = jan,

day = "10",

doi = "10.1002/anie.201004461",

language = "English",

volume = "50",

pages = "486--490",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "2",

}

TY - JOUR

T1 - Highly efficient extraction of sulfate ions with a tripodal hexaurea receptor

AU - Jia, Chuandong

AU - Wu, Biao

AU - Li, Shaoguang

AU - Huang, Xiaojuan

AU - Zhao, Qilong

AU - Li, Qian Shu

AU - Yang, Xiao Juan

PY - 2011/1/10

Y1 - 2011/1/10

N2 - Fatal extraction: The Hofmeister bias for sulfate ions in aqueous environments can be overcome by using a tripodal hexaurea receptor (L) that completely encapsulates the sulfate ion in a complementary cavity protected by hydrophobic aromatic rings (see picture; C-gray, N-blue, O-red, S-yellow). Almost quantitative extraction of sulfate ions from an aqueous to an organic phase is achieved when this receptor is used as a liquid-liquid extractant.

AB - Fatal extraction: The Hofmeister bias for sulfate ions in aqueous environments can be overcome by using a tripodal hexaurea receptor (L) that completely encapsulates the sulfate ion in a complementary cavity protected by hydrophobic aromatic rings (see picture; C-gray, N-blue, O-red, S-yellow). Almost quantitative extraction of sulfate ions from an aqueous to an organic phase is achieved when this receptor is used as a liquid-liquid extractant.

KW - anion recognition

KW - chelate effect

KW - host-guest chemistry

KW - hydrophobic effect

KW - receptors

UR - http://www.scopus.com/inward/record.url?scp=78650362969&partnerID=8YFLogxK

U2 - 10.1002/anie.201004461

DO - 10.1002/anie.201004461

M3 - Article

C2 - 21132821

AN - SCOPUS:78650362969

SN - 1433-7851

VL - 50

SP - 486

EP - 490

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 2

ER -

Highly efficient extraction of sulfate ions with a tripodal hexaurea receptor

摘要

访问文件

其它文件与链接

指纹

引用此