摘要
1,3-Dimesityl-propane-1,3-dione was synthesized in high yield, via a stable intermediate (its aluminum complex) from malonyl dichloride and mesitylene by Friedel-Crafts reaction using anhydrous aluminum chloride as catalyst. The intermediate aluminum complex was isolated and characterized by X-ray diffraction analysis, which decomposed upon reflux in concentrate hydrochloric acid to give the title compound.
源语言 | 英语 |
---|---|
页(从-至) | 2349-2356 |
页数 | 8 |
期刊 | Synthetic Communications |
卷 | 38 |
期 | 14 |
DOI | |
出版状态 | 已出版 - 1月 2008 |
已对外发布 | 是 |
指纹
探究 'High-yield synthesis of 1,3-dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate' 的科研主题。它们共同构成独一无二的指纹。引用此
Zhang, C., Yang, P., Yang, Y., Huang, X., Yang, X. J., & Wu, B. (2008). High-yield synthesis of 1,3-dimesityl-propane-1,3-dione: Isolation of its aluminum complex as a stable intermediate. Synthetic Communications, 38(14), 2349-2356. https://doi.org/10.1080/00397910802138702