High-rate charge-carrier transport in porphyrin covalent organic frameworks: Switching from hole to electron to ambipolar conduction

Xiao Feng, Lili Liu, Yoshihito Honsho, Akinori Saeki, Shu Seki, Stephan Irle*, Yuping Dong, Atsushi Nagai, Donglin Jiang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

347 引用 (Scopus)

摘要

Well conducted: A two-dimensional porphyrin covalent organic framework is described. Owing to the eclipsed stacking alignment, the framework is conductive and allows high-rate carrier transport through the porphyrin columns (see picture). The central metal in the porphyrin rings changes the conducting nature of the material from hole to electron, and to ambipolar conduction. It also drives the high on-off ratio photoconductivity of the framework.

源语言英语
页(从-至)2618-2622
页数5
期刊Angewandte Chemie - International Edition
51
11
DOI
出版状态已出版 - 12 3月 2012

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