TY - JOUR
T1 - High-entropy (La0.2Nd0.2Sm0.2Gd0.2Yb0.2)2(Zr0.75Ce0.25)2O7 thermal barrier coating material with significantly enhanced fracture toughness
AU - GUO, Donghui
AU - ZHOU, Feifei
AU - XU, Baosheng
AU - WANG, Yiguang
AU - WANG, You
N1 - Publisher Copyright:
© 2022 Chinese Society of Aeronautics and Astronautics
PY - 2023/4
Y1 - 2023/4
N2 - Poor fracture toughness leads to premature failure of La2(Zr0.75Ce0.25)2O7 (LCZ) thermal barrier coatings in an elevated temperature service environment. A novel coating material, namely (La0.2Nd0.2Sm0.2Gd0.2Yb0.2)2(Zr0.75Ce0.25)2O7 (LNSGY) based on the high-entropy concept, was successfully fabricated by solid-state sintering. The microstructure of LCZ and LNSGY was investigated by X-Ray Diffraction (XRD), Raman Spectrometer (RS), Transmission Electronic Microscopy (TEM) and Scanning Electron Microscopy (SEM). The fracture toughness of the LCZ and LNSGY ceramics was evaluated. The LNSGY has excellent high-temperature phase stability, and the grain size of LNSGY ceramic is smaller than that of LCZ ceramic at an elevated temperature due to the sluggish diffusion effect. Compared with LCZ (fracture toughness is (1.4 ± 0.1) MPa∙m1/2), the fracture toughness of LNSGY is significantly enhanced (fracture toughness is (2.0 ± 0.3) MPa∙m1/2). Therefore, the LNSGY can be a promising advanced thermal barrier coating material in the future.
AB - Poor fracture toughness leads to premature failure of La2(Zr0.75Ce0.25)2O7 (LCZ) thermal barrier coatings in an elevated temperature service environment. A novel coating material, namely (La0.2Nd0.2Sm0.2Gd0.2Yb0.2)2(Zr0.75Ce0.25)2O7 (LNSGY) based on the high-entropy concept, was successfully fabricated by solid-state sintering. The microstructure of LCZ and LNSGY was investigated by X-Ray Diffraction (XRD), Raman Spectrometer (RS), Transmission Electronic Microscopy (TEM) and Scanning Electron Microscopy (SEM). The fracture toughness of the LCZ and LNSGY ceramics was evaluated. The LNSGY has excellent high-temperature phase stability, and the grain size of LNSGY ceramic is smaller than that of LCZ ceramic at an elevated temperature due to the sluggish diffusion effect. Compared with LCZ (fracture toughness is (1.4 ± 0.1) MPa∙m1/2), the fracture toughness of LNSGY is significantly enhanced (fracture toughness is (2.0 ± 0.3) MPa∙m1/2). Therefore, the LNSGY can be a promising advanced thermal barrier coating material in the future.
KW - Fracture toughness
KW - High-entropy ceramics
KW - High-temperature phase stability
KW - Rare-earth zirconate
KW - Thermal barrier coatings
UR - http://www.scopus.com/inward/record.url?scp=85149735662&partnerID=8YFLogxK
U2 - 10.1016/j.cja.2022.12.001
DO - 10.1016/j.cja.2022.12.001
M3 - Article
AN - SCOPUS:85149735662
SN - 1000-9361
VL - 36
SP - 556
EP - 564
JO - Chinese Journal of Aeronautics
JF - Chinese Journal of Aeronautics
IS - 4
ER -