High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)

Zhi Qi; Wenchao Zhang; Rongjie Yang

High-efficiency flame retardency of epoxy resin composites with perfect T₈ caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)

Zhi Qi, Wenchao Zhang, Rongjie Yang

材料学院

Beijing Institute of Technology

科研成果: 会议稿件 › 论文 › 同行评审

摘要

Three hosphorus containing polyhedral oligomeric silsesquioxanes (POSS) with perfect T₈ caged structures were synthesized successfully by the addition reaction between octa vinyl POSS and diphenylphosphine (DPP), diphenylpsphine oxide (DPOP),or 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO). The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardancy performance and flame retardancy mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed through the condensed phase analysis and gaseous phase analysis.

源语言	英语
出版状态	已出版 - 2016
活动	Foreign Language Association of Maine Annual Conference, FLAME 2016 - Portland, 美国期限: 3 3月 2016 → 4 3月 2016

会议

会议	Foreign Language Association of Maine Annual Conference, FLAME 2016
国家/地区	美国
市	Portland
时期	3/03/16 → 4/03/16

其它文件与链接

链接到 Scopus 的出版物

引用此

@conference{d7b3a224c8a544e399e84bcccbb8124a,

title = "High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)",

abstract = "Three hosphorus containing polyhedral oligomeric silsesquioxanes (POSS) with perfect T8 caged structures were synthesized successfully by the addition reaction between octa vinyl POSS and diphenylphosphine (DPP), diphenylpsphine oxide (DPOP),or 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO). The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardancy performance and flame retardancy mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed through the condensed phase analysis and gaseous phase analysis.",

author = "Zhi Qi and Wenchao Zhang and Rongjie Yang",

year = "2016",

language = "English",

note = "Foreign Language Association of Maine Annual Conference, FLAME 2016 ; Conference date: 03-03-2016 Through 04-03-2016",

}

TY - CONF

T1 - High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)

AU - Qi, Zhi

AU - Zhang, Wenchao

AU - Yang, Rongjie

PY - 2016

Y1 - 2016

N2 - Three hosphorus containing polyhedral oligomeric silsesquioxanes (POSS) with perfect T8 caged structures were synthesized successfully by the addition reaction between octa vinyl POSS and diphenylphosphine (DPP), diphenylpsphine oxide (DPOP),or 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO). The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardancy performance and flame retardancy mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed through the condensed phase analysis and gaseous phase analysis.

AB - Three hosphorus containing polyhedral oligomeric silsesquioxanes (POSS) with perfect T8 caged structures were synthesized successfully by the addition reaction between octa vinyl POSS and diphenylphosphine (DPP), diphenylpsphine oxide (DPOP),or 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO). The impacts of DPP-POSS, DPOP-POSS, and DOPO-POSS on the pyrolysis and fire behavior of an epoxy resin (DGEBA/DDS) were investigated under temperature programmed heating (TGA-FTIR), forced flaming conditions (cone calorimeter) and small flame conditions (LOI and UL-94). The flame retardancy performance and flame retardancy mechanisms of DPP-POSS, DPOP-POSS, and DOPO-POSS were assessed and discussed through the condensed phase analysis and gaseous phase analysis.

UR - http://www.scopus.com/inward/record.url?scp=85014172873&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:85014172873

T2 - Foreign Language Association of Maine Annual Conference, FLAME 2016

Y2 - 3 March 2016 through 4 March 2016

ER -

High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)

摘要

会议

其它文件与链接

指纹

引用此

High-efficiency flame retardency of epoxy resin composites with perfect T₈ caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs)