Fan, Z., Bosman, M., Huang, Z., Chen, Y., Ling, C., Wu, L., Akimov, Y. A., Laskowski, R., Chen, B., Ercius, P., Zhang, J., Qi, X., Goh, M. H., Ge, Y., Zhang, Z., Niu, W., Wang, J., Zheng, H., & Zhang, H. (2020). Heterophase fcc-2H-fcc gold nanorods. Nature Communications, 11(1), 文章 3293. https://doi.org/10.1038/s41467-020-17068-w
Fan, Zhanxi ; Bosman, Michel ; Huang, Zhiqi 等. / Heterophase fcc-2H-fcc gold nanorods. 在: Nature Communications. 2020 ; 卷 11, 号码 1.
@article{26c0b5cd345b4dbe9beafadfc7d1f423,
title = "Heterophase fcc-2H-fcc gold nanorods",
abstract = "The crystal phase-based heterostructures of noble metal nanomaterials are of great research interest for various applications, such as plasmonics and catalysis. However, the synthesis of unusual crystal phases of noble metals still remains a great challenge, making the construction of heterophase noble metal nanostructures difficult. Here, we report a one-pot wet-chemical synthesis of well-defined heterophase fcc-2H-fcc gold nanorods (fcc: face-centred cubic; 2H: hexagonal close-packed with stacking sequence of “AB”) at mild conditions. Single particle-level experiments and theoretical investigations reveal that the heterophase gold nanorods demonstrate a distinct optical property compared to that of the conventional fcc gold nanorods. Moreover, the heterophase gold nanorods possess superior electrocatalytic activity for the carbon dioxide reduction reaction over their fcc counterparts under ambient conditions. First-principles calculations suggest that the boosted catalytic performance stems from the energetically favourable adsorption of reaction intermediates, endowed by the unique heterophase characteristic of gold nanorods.",
author = "Zhanxi Fan and Michel Bosman and Zhiqi Huang and Ye Chen and Chongyi Ling and Lin Wu and Akimov, {Yuriy A.} and Robert Laskowski and Bo Chen and Peter Ercius and Jian Zhang and Xiaoying Qi and Goh, {Min Hao} and Yiyao Ge and Zhicheng Zhang and Wenxin Niu and Jinlan Wang and Haimei Zheng and Hua Zhang",
note = "Publisher Copyright: {\textcopyright} 2020, The Author(s).",
year = "2020",
month = dec,
day = "1",
doi = "10.1038/s41467-020-17068-w",
language = "English",
volume = "11",
journal = "Nature Communications",
issn = "2041-1723",
publisher = "Nature Publishing Group",
number = "1",
}
Fan, Z, Bosman, M, Huang, Z, Chen, Y, Ling, C, Wu, L, Akimov, YA, Laskowski, R, Chen, B, Ercius, P, Zhang, J, Qi, X, Goh, MH, Ge, Y, Zhang, Z, Niu, W, Wang, J, Zheng, H & Zhang, H 2020, 'Heterophase fcc-2H-fcc gold nanorods', Nature Communications, 卷 11, 号码 1, 3293. https://doi.org/10.1038/s41467-020-17068-w
Heterophase fcc-2H-fcc gold nanorods. / Fan, Zhanxi; Bosman, Michel
; Huang, Zhiqi 等.
在:
Nature Communications, 卷 11, 号码 1, 3293, 01.12.2020.
科研成果: 期刊稿件 › 文章 › 同行评审
TY - JOUR
T1 - Heterophase fcc-2H-fcc gold nanorods
AU - Fan, Zhanxi
AU - Bosman, Michel
AU - Huang, Zhiqi
AU - Chen, Ye
AU - Ling, Chongyi
AU - Wu, Lin
AU - Akimov, Yuriy A.
AU - Laskowski, Robert
AU - Chen, Bo
AU - Ercius, Peter
AU - Zhang, Jian
AU - Qi, Xiaoying
AU - Goh, Min Hao
AU - Ge, Yiyao
AU - Zhang, Zhicheng
AU - Niu, Wenxin
AU - Wang, Jinlan
AU - Zheng, Haimei
AU - Zhang, Hua
N1 - Publisher Copyright:
© 2020, The Author(s).
PY - 2020/12/1
Y1 - 2020/12/1
N2 - The crystal phase-based heterostructures of noble metal nanomaterials are of great research interest for various applications, such as plasmonics and catalysis. However, the synthesis of unusual crystal phases of noble metals still remains a great challenge, making the construction of heterophase noble metal nanostructures difficult. Here, we report a one-pot wet-chemical synthesis of well-defined heterophase fcc-2H-fcc gold nanorods (fcc: face-centred cubic; 2H: hexagonal close-packed with stacking sequence of “AB”) at mild conditions. Single particle-level experiments and theoretical investigations reveal that the heterophase gold nanorods demonstrate a distinct optical property compared to that of the conventional fcc gold nanorods. Moreover, the heterophase gold nanorods possess superior electrocatalytic activity for the carbon dioxide reduction reaction over their fcc counterparts under ambient conditions. First-principles calculations suggest that the boosted catalytic performance stems from the energetically favourable adsorption of reaction intermediates, endowed by the unique heterophase characteristic of gold nanorods.
AB - The crystal phase-based heterostructures of noble metal nanomaterials are of great research interest for various applications, such as plasmonics and catalysis. However, the synthesis of unusual crystal phases of noble metals still remains a great challenge, making the construction of heterophase noble metal nanostructures difficult. Here, we report a one-pot wet-chemical synthesis of well-defined heterophase fcc-2H-fcc gold nanorods (fcc: face-centred cubic; 2H: hexagonal close-packed with stacking sequence of “AB”) at mild conditions. Single particle-level experiments and theoretical investigations reveal that the heterophase gold nanorods demonstrate a distinct optical property compared to that of the conventional fcc gold nanorods. Moreover, the heterophase gold nanorods possess superior electrocatalytic activity for the carbon dioxide reduction reaction over their fcc counterparts under ambient conditions. First-principles calculations suggest that the boosted catalytic performance stems from the energetically favourable adsorption of reaction intermediates, endowed by the unique heterophase characteristic of gold nanorods.
UR - http://www.scopus.com/inward/record.url?scp=85087407866&partnerID=8YFLogxK
U2 - 10.1038/s41467-020-17068-w
DO - 10.1038/s41467-020-17068-w
M3 - Article
C2 - 32620898
AN - SCOPUS:85087407866
SN - 2041-1723
VL - 11
JO - Nature Communications
JF - Nature Communications
IS - 1
M1 - 3293
ER -
Fan Z, Bosman M, Huang Z, Chen Y, Ling C, Wu L 等. Heterophase fcc-2H-fcc gold nanorods. Nature Communications. 2020 12月 1;11(1):3293. doi: 10.1038/s41467-020-17068-w
