Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks

Gang Zhao; Chunlin He; Dheeraj Kumar; Joseph P. Hooper; Gregory H. Imler; Damon A. Parrish; Jean'ne M. Shreeve

doi:10.1016/j.cej.2019.02.192

Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks

Gang Zhao, Chunlin He, Dheeraj Kumar, Joseph P. Hooper, Gregory H. Imler, Damon A. Parrish, Jean'ne M. Shreeve^*

^*此作品的通讯作者

材料学院

科研成果: 期刊稿件 › 文章 › 同行评审

19 引用（Scopus）

摘要

In order to deal with biological weapons effectively, agent defeat weapons (ADWs) have been developed to destroy or neutralize the active agents in the resulting plume by releasing large amounts of strong biocides upon detonation. Based on the strategy of coupling of an energetic building block and a biocidal building block, several functional energetic materials were synthesized and fully characterized. All of the compounds have high densities (2.50–2.94 g/cm³), and high iodine contents (57.96 and 76.32%), making them good candidates as biocidal agents. Compounds 4 and 9 exhibit good detonation performances (4: D_v = 3679 m s⁻¹; P = 8.07 GPa and 9: D_v = 4044 m s⁻¹; P = 8.70 GPa) (CHEETAH 7) and their high iodine content suggests their promise as energetic biocides.

源语言	英语
页（从-至）	244-251
页数	8
期刊	Chemical Engineering Journal
卷	368
DOI	https://doi.org/10.1016/j.cej.2019.02.192
出版状态	已出版 - 15 7月 2019

访问文件

10.1016/j.cej.2019.02.192

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{abb09d4cae264a76a63723be59805d6d,

title = "Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks",

abstract = "In order to deal with biological weapons effectively, agent defeat weapons (ADWs) have been developed to destroy or neutralize the active agents in the resulting plume by releasing large amounts of strong biocides upon detonation. Based on the strategy of coupling of an energetic building block and a biocidal building block, several functional energetic materials were synthesized and fully characterized. All of the compounds have high densities (2.50–2.94 g/cm3), and high iodine contents (57.96 and 76.32%), making them good candidates as biocidal agents. Compounds 4 and 9 exhibit good detonation performances (4: Dv = 3679 m s−1; P = 8.07 GPa and 9: Dv = 4044 m s−1; P = 8.70 GPa) (CHEETAH 7) and their high iodine content suggests their promise as energetic biocides.",

keywords = "Biocidal materials, Biocidal polyiodo building blocks, Coupling, Energetic building blocks, Energetic materials",

author = "Gang Zhao and Chunlin He and Dheeraj Kumar and Hooper, {Joseph P.} and Imler, {Gregory H.} and Parrish, {Damon A.} and Shreeve, {Jean'ne M.}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2019",

month = jul,

day = "15",

doi = "10.1016/j.cej.2019.02.192",

language = "English",

volume = "368",

pages = "244--251",

journal = "Chemical Engineering Journal",

issn = "1385-8947",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks

AU - Zhao, Gang

AU - He, Chunlin

AU - Kumar, Dheeraj

AU - Hooper, Joseph P.

AU - Imler, Gregory H.

AU - Parrish, Damon A.

AU - Shreeve, Jean'ne M.

PY - 2019/7/15

Y1 - 2019/7/15

N2 - In order to deal with biological weapons effectively, agent defeat weapons (ADWs) have been developed to destroy or neutralize the active agents in the resulting plume by releasing large amounts of strong biocides upon detonation. Based on the strategy of coupling of an energetic building block and a biocidal building block, several functional energetic materials were synthesized and fully characterized. All of the compounds have high densities (2.50–2.94 g/cm3), and high iodine contents (57.96 and 76.32%), making them good candidates as biocidal agents. Compounds 4 and 9 exhibit good detonation performances (4: Dv = 3679 m s−1; P = 8.07 GPa and 9: Dv = 4044 m s−1; P = 8.70 GPa) (CHEETAH 7) and their high iodine content suggests their promise as energetic biocides.

AB - In order to deal with biological weapons effectively, agent defeat weapons (ADWs) have been developed to destroy or neutralize the active agents in the resulting plume by releasing large amounts of strong biocides upon detonation. Based on the strategy of coupling of an energetic building block and a biocidal building block, several functional energetic materials were synthesized and fully characterized. All of the compounds have high densities (2.50–2.94 g/cm3), and high iodine contents (57.96 and 76.32%), making them good candidates as biocidal agents. Compounds 4 and 9 exhibit good detonation performances (4: Dv = 3679 m s−1; P = 8.07 GPa and 9: Dv = 4044 m s−1; P = 8.70 GPa) (CHEETAH 7) and their high iodine content suggests their promise as energetic biocides.

KW - Biocidal materials

KW - Biocidal polyiodo building blocks

KW - Coupling

KW - Energetic building blocks

KW - Energetic materials

UR - http://www.scopus.com/inward/record.url?scp=85062098827&partnerID=8YFLogxK

U2 - 10.1016/j.cej.2019.02.192

DO - 10.1016/j.cej.2019.02.192

M3 - Article

AN - SCOPUS:85062098827

SN - 1385-8947

VL - 368

SP - 244

EP - 251

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

ER -

Functional energetic biocides by coupling of energetic and biocidal polyiodo building blocks

摘要

访问文件

其它文件与链接

指纹

引用此