Fluorination of fluoro-cyclobutene with high-valency metal fluoride

Junji Mizukado*, Yasuhisa Matsukawa, Heng Dao Quan, Masanori Tamura, Akira Sekiya

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

9 引用 (Scopus)

摘要

Fluorinations of 1,4,4-trifluorocyclobutene and 3,3,4,4- tetrafluorocyclobutene using high-valency metal fluorides such as CoF 3, MnF3, AgF2, CeF4 and KCoF 4, and elemental fluorine were examined. In these reactions with CoF3 and MnF3, vic-difluorination proceeded mainly. While, 1,4,4-trifluorocyclobutene yielded 3,3,4,4-tetrafluorocyclobutene, and 3,3,4,4-tetrafluorocyclobutene yielded 1,3,3,4,4-pentafluorocyclobutene mainly in the case of AgF2. The further fluorinated products were increased under severer conditions. Also, the plausible reaction mechanism was suggested.

源语言英语
页(从-至)79-84
页数6
期刊Journal of Fluorine Chemistry
127
1
DOI
出版状态已出版 - 1月 2006
已对外发布

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