First-principles study on the surface energies of rutile TiO2(110) vs (011)-2×1 surfaces

Feng Yuan, Shi Xiang Lu, Wen Guo Xu, Hai Feng Zhang, Tao Ning

科研成果: 书/报告/会议事项章节会议稿件同行评审

2 引用 (Scopus)

摘要

First-principles calculations based on density functional theory have been used to study the surface energies of the rutile TiO2(110) and (011)-2×1 surfaces. We investigate the effect of the slab thickness on the predicted surface energy and find that slab thicknesses of at least 5 layers are necessary to converge the surface energy to within 0.01 J/m2 for both rutile TiO2(110) and (011)-2×1 surfaces. For the rutile TiO2(110) surface, it should be noted that the surface energy oscillates with the number of layers (odd-even oscillations). However, the calculated surface energies of the rutile TiO2(011)-2×1 surface are closer to the linear relationship for the number of layers larger than 4. Finally, our calculated results indicate that the rutile TiO2(011)-2×1 surface has a significantly higher surface energy than the rutile TiO2(110) surface.

源语言英语
主期刊名Material Science and Environmental Engineering
出版商Trans Tech Publications
113-117
页数5
ISBN(印刷版)9783038351009
DOI
出版状态已出版 - 2014
活动2nd International Conference on Material Science and Environmental Engineering, MSEE 2014 - Changsha, Hunan, 中国
期限: 21 3月 201423 3月 2014

出版系列

姓名Advanced Materials Research
937
ISSN(印刷版)1022-6680

会议

会议2nd International Conference on Material Science and Environmental Engineering, MSEE 2014
国家/地区中国
Changsha, Hunan
时期21/03/1423/03/14

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