TY - JOUR
T1 - Fabrication of Aunanoparticle@mSiO2@Y2O3:Eu nanocomposites with enhanced fluorescence
AU - Li, Huiqin
AU - Kang, Jianmiao
AU - Yang, Jianhui
AU - Wu, Biao
N1 - Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2016/7/15
Y1 - 2016/7/15
N2 - Herein, Aunanoparticle@mSiO2@Y2O3:Eu nanocomposites are synthesized through layer-by-layer assembly technology. Aunanoparticle@mSiO2 core-shell nanospheres were prepared at first in the presence of CTAB in aqueous solution system by the modified one-pot method. A chemical precipitation method and a succeeding calcination process were adopted to the growth of Y2O3:Eu shells on the surfaces of Aunanoparticle@mSiO2 core-shell nanospheres. The structure, morphology and composition of the nanocomposites were confirmed by XRD, TEM and UV-vis absorption spectrum. The prepared Aunanoparticle@mSiO2@Y2O3:Eu nanocomposites have showed the emission intensity enhances to 6.23 times at 30 nm thickness of the silica spacer between the core of Au nanoparticle and the shell of Y2O3:Eu. According to the observations of fluorescent lifetime and the modeling of local electric field, the metal-enhanced and quenched fluorescence is closely related with the enhancement of excitation and radiative decay rate and the quenching by NRET comes as a result of competition between the distance-dependent mechanisms. This kind of multifunctional inorganic material will be widely used in electronics, biology and medical drug loading, etc.
AB - Herein, Aunanoparticle@mSiO2@Y2O3:Eu nanocomposites are synthesized through layer-by-layer assembly technology. Aunanoparticle@mSiO2 core-shell nanospheres were prepared at first in the presence of CTAB in aqueous solution system by the modified one-pot method. A chemical precipitation method and a succeeding calcination process were adopted to the growth of Y2O3:Eu shells on the surfaces of Aunanoparticle@mSiO2 core-shell nanospheres. The structure, morphology and composition of the nanocomposites were confirmed by XRD, TEM and UV-vis absorption spectrum. The prepared Aunanoparticle@mSiO2@Y2O3:Eu nanocomposites have showed the emission intensity enhances to 6.23 times at 30 nm thickness of the silica spacer between the core of Au nanoparticle and the shell of Y2O3:Eu. According to the observations of fluorescent lifetime and the modeling of local electric field, the metal-enhanced and quenched fluorescence is closely related with the enhancement of excitation and radiative decay rate and the quenching by NRET comes as a result of competition between the distance-dependent mechanisms. This kind of multifunctional inorganic material will be widely used in electronics, biology and medical drug loading, etc.
KW - Core-spacer-shell structure
KW - Luminescence properties
KW - Mesoporous silica coating
KW - Metal enhanced fluorescence
KW - Nanofabrications
UR - http://www.scopus.com/inward/record.url?scp=84960342632&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2016.02.263
DO - 10.1016/j.jallcom.2016.02.263
M3 - Article
AN - SCOPUS:84960342632
SN - 0925-8388
VL - 673
SP - 283
EP - 288
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
ER -