摘要
Epoxycyclohexyl phenyl polyhedral oligomeric silsesquioxane oligo-mers(cy-ep-Ph-POSS) was synthesized via hydrolytic condensation reaction, which was used to prepare epoxy(EP)/cy-ep-Ph-POSS blends whose thermal, mechanical and flame retardant properties were observed. The results show that cy-ep-Ph-POSS is composed of polyhedral oligomeric silsesquioxane containing 6, 8, and 10 silicon atoms. The tensile strength and flexural modulus of EP/cy-ep-Ph-POSS composites are increased by 16% and 10% than those of pure EP. The initial decomposition temperature and the residue of the composites are increased, whose limiting oxygen index reaches 27.6%. Significant improvement in molten droplets during UL-94 is observed. The peak-heat release rate is decreased by 49%. Therefore, cy-ep-Ph-POSS has high application value in improving flame retardancy and mechanical properties of EP.
| 投稿的翻译标题 | Preparation and properties of EP/cy-ep-Ph-POSS blends |
|---|---|
| 源语言 | 繁体中文 |
| 页（从-至） | 6-13 |
| 页数 | 8 |
| 期刊 | Hecheng Shuzhi Ji Suliao/China Synthetic Resin and Plastics |
| 卷 | 38 |
| 期 | 1 |
| DOI | |
| 出版状态 | 已出版 - 25 1月 2021 |
关键词
- Epoxy resin
- Epoxycyclohexyl phenyl polyhedral oligomeric silses-quioxane oligomer
- Flame retardancy
- Mechanical property