He, Y., Tang, P., Hu, Z., He, Q., Zhu, C., Wang, L., Zeng, Q., Golani, P., Gao, G., Fu, W., Huang, Z., Gao, C., Xia, J., Wang, X., Wang, X., Zhu, C., Ramasse, Q. M., Zhang, A., An, B., ... Liu, Z. (2020). Engineering grain boundaries at the 2D limit for the hydrogen evolution reaction. Nature Communications, 11(1), 文章 57. https://doi.org/10.1038/s41467-019-13631-2
@article{091b6ad8fe484409830776cf42c312e4,
title = "Engineering grain boundaries at the 2D limit for the hydrogen evolution reaction",
abstract = "Atom-thin transition metal dichalcogenides (TMDs) have emerged as fascinating materials and key structures for electrocatalysis. So far, their edges, dopant heteroatoms and defects have been intensively explored as active sites for the hydrogen evolution reaction (HER) to split water. However, grain boundaries (GBs), a key type of defects in TMDs, have been overlooked due to their low density and large structural variations. Here, we demonstrate the synthesis of wafer-size atom-thin TMD films with an ultra-high-density of GBs, up to ~1012 cm−2. We propose a climb and drive 0D/2D interaction to explain the underlying growth mechanism. The electrocatalytic activity of the nanograin film is comprehensively examined by micro-electrochemical measurements, showing an excellent hydrogen-evolution performance (onset potential: −25 mV and Tafel slope: 54 mV dec−1), thus indicating an intrinsically high activation of the TMD GBs.",
author = "Yongmin He and Pengyi Tang and Zhili Hu and Qiyuan He and Chao Zhu and Luqing Wang and Qingsheng Zeng and Prafful Golani and Guanhui Gao and Wei Fu and Zhiqi Huang and Caitian Gao and Juan Xia and Xingli Wang and Xuewen Wang and Chao Zhu and Ramasse, {Quentin M.} and Ao Zhang and Boxing An and Yongzhe Zhang and Sara Mart{\'i}-S{\'a}nchez and Morante, {Joan Ramon} and Liang Wang and Tay, {Beng Kang} and Yakobson, {Boris I.} and Achim Trampert and Hua Zhang and Minghong Wu and Wang, {Qi Jie} and Jordi Arbiol and Zheng Liu",
note = "Publisher Copyright: {\textcopyright} 2020, The Author(s).",
year = "2020",
month = dec,
day = "1",
doi = "10.1038/s41467-019-13631-2",
language = "English",
volume = "11",
journal = "Nature Communications",
issn = "2041-1723",
publisher = "Nature Publishing Group",
number = "1",
}
He, Y, Tang, P, Hu, Z, He, Q, Zhu, C, Wang, L, Zeng, Q, Golani, P, Gao, G, Fu, W, Huang, Z, Gao, C, Xia, J, Wang, X, Wang, X, Zhu, C, Ramasse, QM, Zhang, A, An, B, Zhang, Y, Martí-Sánchez, S, Morante, JR, Wang, L, Tay, BK, Yakobson, BI, Trampert, A, Zhang, H, Wu, M, Wang, QJ, Arbiol, J & Liu, Z 2020, 'Engineering grain boundaries at the 2D limit for the hydrogen evolution reaction', Nature Communications, 卷 11, 号码 1, 57. https://doi.org/10.1038/s41467-019-13631-2
TY - JOUR
T1 - Engineering grain boundaries at the 2D limit for the hydrogen evolution reaction
AU - He, Yongmin
AU - Tang, Pengyi
AU - Hu, Zhili
AU - He, Qiyuan
AU - Zhu, Chao
AU - Wang, Luqing
AU - Zeng, Qingsheng
AU - Golani, Prafful
AU - Gao, Guanhui
AU - Fu, Wei
AU - Huang, Zhiqi
AU - Gao, Caitian
AU - Xia, Juan
AU - Wang, Xingli
AU - Wang, Xuewen
AU - Zhu, Chao
AU - Ramasse, Quentin M.
AU - Zhang, Ao
AU - An, Boxing
AU - Zhang, Yongzhe
AU - Martí-Sánchez, Sara
AU - Morante, Joan Ramon
AU - Wang, Liang
AU - Tay, Beng Kang
AU - Yakobson, Boris I.
AU - Trampert, Achim
AU - Zhang, Hua
AU - Wu, Minghong
AU - Wang, Qi Jie
AU - Arbiol, Jordi
AU - Liu, Zheng
N1 - Publisher Copyright:
© 2020, The Author(s).
PY - 2020/12/1
Y1 - 2020/12/1
N2 - Atom-thin transition metal dichalcogenides (TMDs) have emerged as fascinating materials and key structures for electrocatalysis. So far, their edges, dopant heteroatoms and defects have been intensively explored as active sites for the hydrogen evolution reaction (HER) to split water. However, grain boundaries (GBs), a key type of defects in TMDs, have been overlooked due to their low density and large structural variations. Here, we demonstrate the synthesis of wafer-size atom-thin TMD films with an ultra-high-density of GBs, up to ~1012 cm−2. We propose a climb and drive 0D/2D interaction to explain the underlying growth mechanism. The electrocatalytic activity of the nanograin film is comprehensively examined by micro-electrochemical measurements, showing an excellent hydrogen-evolution performance (onset potential: −25 mV and Tafel slope: 54 mV dec−1), thus indicating an intrinsically high activation of the TMD GBs.
AB - Atom-thin transition metal dichalcogenides (TMDs) have emerged as fascinating materials and key structures for electrocatalysis. So far, their edges, dopant heteroatoms and defects have been intensively explored as active sites for the hydrogen evolution reaction (HER) to split water. However, grain boundaries (GBs), a key type of defects in TMDs, have been overlooked due to their low density and large structural variations. Here, we demonstrate the synthesis of wafer-size atom-thin TMD films with an ultra-high-density of GBs, up to ~1012 cm−2. We propose a climb and drive 0D/2D interaction to explain the underlying growth mechanism. The electrocatalytic activity of the nanograin film is comprehensively examined by micro-electrochemical measurements, showing an excellent hydrogen-evolution performance (onset potential: −25 mV and Tafel slope: 54 mV dec−1), thus indicating an intrinsically high activation of the TMD GBs.
UR - http://www.scopus.com/inward/record.url?scp=85077445109&partnerID=8YFLogxK
U2 - 10.1038/s41467-019-13631-2
DO - 10.1038/s41467-019-13631-2
M3 - Article
C2 - 31896753
AN - SCOPUS:85077445109
SN - 2041-1723
VL - 11
JO - Nature Communications
JF - Nature Communications
IS - 1
M1 - 57
ER -
