TY - JOUR
T1 - Effects of water immersion and pre-oxidation on re-ignition characteristics of non-caking coal
AU - Liu, Qiqi
AU - Sun, Lulu
AU - Zhang, Yanbo
AU - Liu, Zhenyi
AU - Ma, Jiayu
N1 - Publisher Copyright:
© 2023
PY - 2023/11/1
Y1 - 2023/11/1
N2 - Coal spontaneous combustion (CSC) in waterlogged goafs has become an essential threat to coal mine safety production, so it is necessary to comprehensively and deeply evaluate the re-ignition characteristics of residual coal after water immersion and pre-oxidation. The re-ignition process of non-caking coal under the influence of water immersion and pre-oxidation was tested using a temperature-programmed test system (TPTS), and the spontaneous combustion characteristic parameters and limit characteristic parameters of low-temperature oxidation were calculated. The results show that the spontaneous combustion characteristic parameters such as CO production rate, oxygen consumption rate, and heat release intensity positively correlate with temperature. The minimum float coal thickness and lower limit oxygen concentration show a trend of increasing and then decreasing with the temperature increase, while the maximal air leakage intensity is the opposite. In addition, the expansion of pores and cracks caused by water immersion and pre-oxidation processes and the increase of unstable functional groups promote the oxygen consumption and heat generation of immersed and oxidized coal, which reduces the characteristic temperature, and activation energy, and limit characteristic parameters. Meanwhile, water immersion and pre-oxidation can synergistically accelerate the low-temperature oxidation process of non-caking coal, which significantly increases the CSC risk of coal O140I30 and coal O90I30. The results enrich the research on the characteristics of water immersed and oxidation coals re-ignition, which may be applied to prevent CSC in the future.
AB - Coal spontaneous combustion (CSC) in waterlogged goafs has become an essential threat to coal mine safety production, so it is necessary to comprehensively and deeply evaluate the re-ignition characteristics of residual coal after water immersion and pre-oxidation. The re-ignition process of non-caking coal under the influence of water immersion and pre-oxidation was tested using a temperature-programmed test system (TPTS), and the spontaneous combustion characteristic parameters and limit characteristic parameters of low-temperature oxidation were calculated. The results show that the spontaneous combustion characteristic parameters such as CO production rate, oxygen consumption rate, and heat release intensity positively correlate with temperature. The minimum float coal thickness and lower limit oxygen concentration show a trend of increasing and then decreasing with the temperature increase, while the maximal air leakage intensity is the opposite. In addition, the expansion of pores and cracks caused by water immersion and pre-oxidation processes and the increase of unstable functional groups promote the oxygen consumption and heat generation of immersed and oxidized coal, which reduces the characteristic temperature, and activation energy, and limit characteristic parameters. Meanwhile, water immersion and pre-oxidation can synergistically accelerate the low-temperature oxidation process of non-caking coal, which significantly increases the CSC risk of coal O140I30 and coal O90I30. The results enrich the research on the characteristics of water immersed and oxidation coals re-ignition, which may be applied to prevent CSC in the future.
KW - Activation energy
KW - Characteristic parameters
KW - Limit parameter
KW - Pre-oxidation
KW - Re-ignition mechanism
KW - Water immersion
UR - http://www.scopus.com/inward/record.url?scp=85169780462&partnerID=8YFLogxK
U2 - 10.1016/j.energy.2023.128616
DO - 10.1016/j.energy.2023.128616
M3 - Article
AN - SCOPUS:85169780462
SN - 0360-5442
VL - 282
JO - Energy
JF - Energy
M1 - 128616
ER -