Effect dehydrants to increasing molecular weight of condensed polylactic acid

Meng Yan Yin, Rong Jie Yang, Ding Hua Li

科研成果: 书/报告/会议事项章节会议稿件同行评审

1 引用 (Scopus)

摘要

The polylactic acid (PLA) was prepared by direct melt polycondensation using lactic acid aqueous solution as raw material. Considering of the difficulty to rule out small molecules of water, magnesium or magnesium methoxide which could react with water were used as dehydrant and added in the PLA polycondensation, respectively. The determination of moisture, GPC and DSC results showed that both the magnesium and magnesium methoxide are effective in dehydration, the molecular weight of final products PLA is significantly improved and the latter is better. Both of them have a good promoting effect on polycondensation reaction to get a higher molecular weight polylactic acid products. For the time of adding magnesium and magnesium methoxide, it is better to add in the late stage of polycondensation reaction rather than early stage. Furthermore, magnesium has a smaller influence on crystallization of PLA, whereas the crystallinity of PLA is greatly reduced after adding magnesium methoxide.

源语言英语
主期刊名Research in Mechanical Engineering and Material Science
出版商Trans Tech Publications Ltd.
525-528
页数4
ISBN(印刷版)9783037859285
DOI
出版状态已出版 - 2014
活动2013 International Conference on Mechanical, Material Engineering, MME 2013 - Shiyan, Hubei, 中国
期限: 23 11月 201324 11月 2013

出版系列

姓名Applied Mechanics and Materials
456
ISSN(印刷版)1660-9336
ISSN(电子版)1662-7482

会议

会议2013 International Conference on Mechanical, Material Engineering, MME 2013
国家/地区中国
Shiyan, Hubei
时期23/11/1324/11/13

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