Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines

Jia Sheng Pan, Rui Zhang*, Shuang Shuang Ma, Li Jun Han, Bao Hua Xu*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

4 引用 (Scopus)

摘要

An easily synthesized ruthenium(II) complex was developed for the direct reductive amination of both aldehydes and ketones with H2 and ammonia. The intramolecular carboxylate-assisted hydrogenation fashion was found compatible with the amination between carbonyl substrates and ammonia, enabling a high selectivity toward primary amines. Varied primary amines were obtained with a turnover numbers (TON) up to 376.

源语言英语
页(从-至)10933-10938
页数6
期刊ChemistrySelect
5
35
DOI
出版状态已出版 - 22 9月 2020
已对外发布

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