Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2 N,N′)cobalt(II) dichloro-methane hemisolvate

Yue Yang, Peiju Yang, Cui Zhang, Biao Wu*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

摘要

The title compound, [CoCl2(C21H17ClN2)]·0.5CH2Cl2, crystallizes from dichloro-methane as a 2:1 solvate [CoCl2L]2·CH2Cl2 (L is 2-chloro-9-mesityl-1,10-phenanthroline). There are two independent CoCl2 L mol-ecules in the asymmetric unit and both mol-ecules have similar conformations. They are connected by a weak C - H⋯π inter-action involving the mesityl ring. The cobalt center is four-coordinated by the two N-atom donors of the bidentate ligand and two chloride ions in a distorted tetra-hedral geometry. The packing of the mol-ecules is stabilized by weak slipped π-π stacking inter-actions between symmetry-related phenanthroline groups.

源语言英语
页(从-至)m623
期刊Acta Crystallographica Section E: Structure Reports Online
64
5
DOI
出版状态已出版 - 30 4月 2008
已对外发布

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Yang, Y., Yang, P., Zhang, C., & Wu, B. (2008). Dichlorido(2-chloro-9-mesityl-1,10-phenanthroline-κ2 N,N′)cobalt(II) dichloro-methane hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 64(5), m623. https://doi.org/10.1107/S1600536808007320