Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

Xin Xiong Li; Lin Jie Zhang; Cai Yan Cui; Rui Hu Wang; Guo Yu Yang

doi:10.1021/acs.inorgchem.8b01528

Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

Xin Xiong Li^*, Lin Jie Zhang, Cai Yan Cui, Rui Hu Wang, Guo Yu Yang

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

53 引用（Scopus）

摘要

Two unprecedented examples of cluster organic frameworks (TBA)₃Cu[V₆O₁₃(L)₂]₂·4DEF (2) (TBA)Ag[V₆O₁₃(L)₂] solvent (3) (TBA = tetrabutylammonium, H₃L = tris(hydroxymethyl)-4-picoline, DEF = N,N′-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.

源语言	英语
页（从-至）	10323-10330
页数	8
期刊	Inorganic Chemistry
卷	57
期	16
DOI	https://doi.org/10.1021/acs.inorgchem.8b01528
出版状态	已出版 - 20 8月 2018

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title = "Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster",

abstract = "Two unprecedented examples of cluster organic frameworks (TBA)3Cu[V6O13(L)2]2·4DEF (2) (TBA)Ag[V6O13(L)2] solvent (3) (TBA = tetrabutylammonium, H3L = tris(hydroxymethyl)-4-picoline, DEF = N,N′-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.",

author = "Li, {Xin Xiong} and Zhang, {Lin Jie} and Cui, {Cai Yan} and Wang, {Rui Hu} and Yang, {Guo Yu}",

note = "Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = aug,

day = "20",

doi = "10.1021/acs.inorgchem.8b01528",

language = "English",

volume = "57",

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T1 - Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

AU - Li, Xin Xiong

AU - Zhang, Lin Jie

AU - Cui, Cai Yan

AU - Wang, Rui Hu

AU - Yang, Guo Yu

PY - 2018/8/20

Y1 - 2018/8/20

N2 - Two unprecedented examples of cluster organic frameworks (TBA)3Cu[V6O13(L)2]2·4DEF (2) (TBA)Ag[V6O13(L)2] solvent (3) (TBA = tetrabutylammonium, H3L = tris(hydroxymethyl)-4-picoline, DEF = N,N′-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.

AB - Two unprecedented examples of cluster organic frameworks (TBA)3Cu[V6O13(L)2]2·4DEF (2) (TBA)Ag[V6O13(L)2] solvent (3) (TBA = tetrabutylammonium, H3L = tris(hydroxymethyl)-4-picoline, DEF = N,N′-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.

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DO - 10.1021/acs.inorgchem.8b01528

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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ER -

Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

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