Defluorination of homologous chlorofluoroethers to chlorofluoroacetates

Heng Dao Quan; Masanori Tamura; Ren Xiao Gao; Akira Sekiya

doi:10.1016/S0022-1139(02)00321-4

Defluorination of homologous chlorofluoroethers to chlorofluoroacetates

Heng Dao Quan, Masanori Tamura, Ren Xiao Gao, Akira Sekiya^*

^*此作品的通讯作者

National Institute of Advanced Industrial Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

The research was focused on the defluorination of chlorofluoroethers to corresponding esters using porous aluminum fluoride (PAF) or MF_n/PAF. In the work up process, the product was easily separated from the reagent. Thus, the reaction would be a practical preparation method for polyfluorinated esters. Trifluoromethyl chlorodifluoroacetate was obtained by the reaction of 1,2-dichlorotrifluoroethyltrifluoromethyl ether with fuming sulfuric acid in 49% yield.

源语言	英语
页（从-至）	131-134
页数	4
期刊	Journal of Fluorine Chemistry
卷	120
期	2
DOI	https://doi.org/10.1016/S0022-1139(02)00321-4
出版状态	已出版 - 1 4月 2003
已对外发布	是

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abstract = "The research was focused on the defluorination of chlorofluoroethers to corresponding esters using porous aluminum fluoride (PAF) or MFn/PAF. In the work up process, the product was easily separated from the reagent. Thus, the reaction would be a practical preparation method for polyfluorinated esters. Trifluoromethyl chlorodifluoroacetate was obtained by the reaction of 1,2-dichlorotrifluoroethyltrifluoromethyl ether with fuming sulfuric acid in 49% yield.",

keywords = "Chlorofluoroether, Defluorination, Porous aluminum fluoride",

author = "Quan, {Heng Dao} and Masanori Tamura and Gao, {Ren Xiao} and Akira Sekiya",

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AU - Quan, Heng Dao

AU - Tamura, Masanori

AU - Gao, Ren Xiao

AU - Sekiya, Akira

PY - 2003/4/1

Y1 - 2003/4/1

N2 - The research was focused on the defluorination of chlorofluoroethers to corresponding esters using porous aluminum fluoride (PAF) or MFn/PAF. In the work up process, the product was easily separated from the reagent. Thus, the reaction would be a practical preparation method for polyfluorinated esters. Trifluoromethyl chlorodifluoroacetate was obtained by the reaction of 1,2-dichlorotrifluoroethyltrifluoromethyl ether with fuming sulfuric acid in 49% yield.

AB - The research was focused on the defluorination of chlorofluoroethers to corresponding esters using porous aluminum fluoride (PAF) or MFn/PAF. In the work up process, the product was easily separated from the reagent. Thus, the reaction would be a practical preparation method for polyfluorinated esters. Trifluoromethyl chlorodifluoroacetate was obtained by the reaction of 1,2-dichlorotrifluoroethyltrifluoromethyl ether with fuming sulfuric acid in 49% yield.

KW - Chlorofluoroether

KW - Defluorination

KW - Porous aluminum fluoride

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JF - Journal of Fluorine Chemistry

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ER -

Defluorination of homologous chlorofluoroethers to chlorofluoroacetates

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