Cubic polyoxometalate-organic molecular cage

Shou Tian Zheng; Jie Zhang; Xin Xiong Li; Wei Hui Fang; Guo Yu Yang

doi:10.1021/ja105986b

Cubic polyoxometalate-organic molecular cage

Shou Tian Zheng, Jie Zhang, Xin Xiong Li, Wei Hui Fang, Guo Yu Yang^*

^*此作品的通讯作者

化学与化工学院

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

365 引用（Scopus）

摘要

Tris(hydroxymethyl)aminomethane (Tris) was successfully grafted onto the surface of a Ni₆-substituted polyoxotungstate formed in situ to further generate a three-connected polyoxometalate building block. The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate-organic molecular cage with high thermal and hydrothermal stability.

源语言	英语
页（从-至）	15102-15103
页数	2
期刊	Journal of the American Chemical Society
卷	132
期	43
DOI	https://doi.org/10.1021/ja105986b
出版状态	已出版 - 3 11月 2010

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title = "Cubic polyoxometalate-organic molecular cage",

abstract = "Tris(hydroxymethyl)aminomethane (Tris) was successfully grafted onto the surface of a Ni6-substituted polyoxotungstate formed in situ to further generate a three-connected polyoxometalate building block. The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate-organic molecular cage with high thermal and hydrothermal stability.",

author = "Zheng, {Shou Tian} and Jie Zhang and Li, {Xin Xiong} and Fang, {Wei Hui} and Yang, {Guo Yu}",

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AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Li, Xin Xiong

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2010/11/3

Y1 - 2010/11/3

N2 - Tris(hydroxymethyl)aminomethane (Tris) was successfully grafted onto the surface of a Ni6-substituted polyoxotungstate formed in situ to further generate a three-connected polyoxometalate building block. The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate-organic molecular cage with high thermal and hydrothermal stability.

AB - Tris(hydroxymethyl)aminomethane (Tris) was successfully grafted onto the surface of a Ni6-substituted polyoxotungstate formed in situ to further generate a three-connected polyoxometalate building block. The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate-organic molecular cage with high thermal and hydrothermal stability.

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Cubic polyoxometalate-organic molecular cage

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