Crystallographic evidence and spin activation for the Russian-doll-type metallofullerene Sc4C2@C80

Mingzhe Nie, Haibing Meng, Chong Zhao, Yuxi Lu, Jie Zhang, Lai Feng*, Chunru Wang, Taishan Wang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

6 引用 (Scopus)

摘要

We report unambiguous crystallographic evidence for the Russian-doll-type metallofullerene Sc4C2@Ih-C8045Sc NMR further demonstrates the tetrahedron arrangement of the Sc4C2cluster. Moreover, the electrochemical test reveals the stable oxidation state of Sc4C2@C80. Hence, the Sc4C2@C80cation radical was studied by electron spin resonance spectroscopy.

源语言英语
页(从-至)10879-10882
页数4
期刊Chemical Communications
56
74
DOI
出版状态已出版 - 21 9月 2020
已对外发布

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