Crystallization-induced emission enhancement of highly electron-deficient dicyanomethylene-bridged triarylboranes

Guanming Liao, Jia Zhang, Xiaoyan Zheng*, Xiaodi Jia, Jialiang Xu, Fenggui Zhao, Nan Wang, Kanglei Liu, Pangkuan Chen, Xiaodong Yin

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

9 引用 (Scopus)

摘要

A highly electron-deficient dicyanomethylene-bridged triarylborane,FMesB-TCN, was reported with a low-lying LUMO and crystallization-induced emission enhancement in its block-shape crystal. DFT calculations revealed lower re-organization energy of the block crystal than that of the weakly emissive acicular crystal. This work explored a novel boron-containing skeleton with interesting optical properties.

源语言英语
页(从-至)7926-7929
页数4
期刊Chemical Communications
57
64
DOI
出版状态已出版 - 18 8月 2021

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