摘要
Because a tridendate dicarboxylato group blockes three coordination sites, the centrosymmetric title zinc oxydiacetate adduct is a binuclear complex. The octahedral geometry is completed by one half of the 4,4'-bipyridine ligand, and by two water molecules that are trans to each other. The dinuclear units are connected by hydrogen bonds; the carboxyl oxygen atoms each form only one hydrogen bond [2.730(3), 2.766(3) Å] and the carbonyl oxygen atoms each form a pair of hydrogen bonds [2.791(4), 2.831(4) Å; 2.811(4), 2.842(4) Å] to furnish a network structure.
源语言 | 英语 |
---|---|
页(从-至) | 321-322 |
页数 | 2 |
期刊 | Main Group Metal Chemistry |
卷 | 25 |
期 | 5 |
DOI | |
出版状态 | 已出版 - 2002 |
已对外发布 | 是 |
指纹
探究 'Crystal structure of di[oxydiacetatozinc(II)].4,4′-bipyridine' 的科研主题。它们共同构成独一无二的指纹。引用此
Tao, J., Yin, X., Zheng, L. S., & Seik, W. N. (2002). Crystal structure of di[oxydiacetatozinc(II)].4,4′-bipyridine. Main Group Metal Chemistry, 25(5), 321-322. https://doi.org/10.1515/MGMC.2002.25.5.321