Crystal structure and performances of the dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate

Xiao Jun Wang; Xiao Peng Zhang; Feng Qin Shang; Zhi Yan Lu; Xia Wang; Xiao Ma; Shao Hua Jin

doi:10.14077/j.issn.1007-7812.2016.04.004

Crystal structure and performances of the dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate

Xiao Jun Wang, Xiao Peng Zhang, Feng Qin Shang, Zhi Yan Lu, Xia Wang, Xiao Ma, Shao Hua Jin^*

^*此作品的通讯作者

材料学院

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

Dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate[Li₂(BTO)(H₂O)₄]_n was prepared and its single crystal was cultured.The single crystal structure was determined by a X-ray single crystal diffractometer. The thermal performance of [Li₂(BTO)(H₂O)₄]_n was studied by differential thermal analysis/thermogravimetry (DTA/TG) technique, and its impact sensitivity and friction sensitivity were measured.The results show that the crystal is triclinic belonging to space group P-1 with crystaphicllogra parameters of a=0.5345(17) nm, b=0.6363(2) nm, c=0.830(3) nm, α=105.904(7), β=98.216(7), γ=111.516(7), V=2.4302 (13) nm³, z=2, D=1.736g/cm³. Its thermal decomposition peak temperature is 349.1℃, the impact sensitivity and friction sensitivity are 71.8 cm and 0, respectively.

源语言	英语
页（从-至）	23-26
页数	4
期刊	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
卷	39
期	4
DOI	https://doi.org/10.14077/j.issn.1007-7812.2016.04.004
出版状态	已出版 - 2016

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@article{0488409613a64b1e8f0d46a00ff2719a,

title = "Crystal structure and performances of the dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate",

abstract = "Dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate[Li2(BTO)(H2O)4]n was prepared and its single crystal was cultured.The single crystal structure was determined by a X-ray single crystal diffractometer. The thermal performance of [Li2(BTO)(H2O)4]n was studied by differential thermal analysis/thermogravimetry (DTA/TG) technique, and its impact sensitivity and friction sensitivity were measured.The results show that the crystal is triclinic belonging to space group P-1 with crystaphicllogra parameters of a=0.5345(17) nm, b=0.6363(2) nm, c=0.830(3) nm, α=105.904(7), β=98.216(7), γ=111.516(7), V=2.4302 (13) nm3, z=2, D=1.736g/cm3. Its thermal decomposition peak temperature is 349.1℃, the impact sensitivity and friction sensitivity are 71.8 cm and 0, respectively.",

keywords = "Crystal structure, Dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate, Energetic material, Sensitivity, Thermal decomposition, [Li(BTO)(HO)]",

author = "Wang, {Xiao Jun} and Zhang, {Xiao Peng} and Shang, {Feng Qin} and Lu, {Zhi Yan} and Xia Wang and Xiao Ma and Jin, {Shao Hua}",

year = "2016",

doi = "10.14077/j.issn.1007-7812.2016.04.004",

language = "English",

volume = "39",

pages = "23--26",

journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

issn = "1007-7812",

publisher = "China Ordnance Industry Corporation",

number = "4",

}

TY - JOUR

T1 - Crystal structure and performances of the dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate

AU - Wang, Xiao Jun

AU - Zhang, Xiao Peng

AU - Shang, Feng Qin

AU - Lu, Zhi Yan

AU - Wang, Xia

AU - Ma, Xiao

AU - Jin, Shao Hua

PY - 2016

Y1 - 2016

N2 - Dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate[Li2(BTO)(H2O)4]n was prepared and its single crystal was cultured.The single crystal structure was determined by a X-ray single crystal diffractometer. The thermal performance of [Li2(BTO)(H2O)4]n was studied by differential thermal analysis/thermogravimetry (DTA/TG) technique, and its impact sensitivity and friction sensitivity were measured.The results show that the crystal is triclinic belonging to space group P-1 with crystaphicllogra parameters of a=0.5345(17) nm, b=0.6363(2) nm, c=0.830(3) nm, α=105.904(7), β=98.216(7), γ=111.516(7), V=2.4302 (13) nm3, z=2, D=1.736g/cm3. Its thermal decomposition peak temperature is 349.1℃, the impact sensitivity and friction sensitivity are 71.8 cm and 0, respectively.

AB - Dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate[Li2(BTO)(H2O)4]n was prepared and its single crystal was cultured.The single crystal structure was determined by a X-ray single crystal diffractometer. The thermal performance of [Li2(BTO)(H2O)4]n was studied by differential thermal analysis/thermogravimetry (DTA/TG) technique, and its impact sensitivity and friction sensitivity were measured.The results show that the crystal is triclinic belonging to space group P-1 with crystaphicllogra parameters of a=0.5345(17) nm, b=0.6363(2) nm, c=0.830(3) nm, α=105.904(7), β=98.216(7), γ=111.516(7), V=2.4302 (13) nm3, z=2, D=1.736g/cm3. Its thermal decomposition peak temperature is 349.1℃, the impact sensitivity and friction sensitivity are 71.8 cm and 0, respectively.

KW - Crystal structure

KW - Dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate

KW - Energetic material

KW - Sensitivity

KW - Thermal decomposition

KW - [Li(BTO)(HO)]

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U2 - 10.14077/j.issn.1007-7812.2016.04.004

DO - 10.14077/j.issn.1007-7812.2016.04.004

M3 - Article

AN - SCOPUS:84991063767

SN - 1007-7812

VL - 39

SP - 23

EP - 26

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 4

ER -

Crystal structure and performances of the dilithium 5, 5'-bistetrazole -1, 1'-diolate tetrahydrate

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