Cp*Rh-based heterometallic metallarectangles: Size-dependent borromean link structures and catalytic acyl transfer

Sheng Li Huang, Yue Jian Lin, T. S.Andy Hor, Guo Xin Jin*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

204 引用 (Scopus)

摘要

A series of CpRh-based functional metallarectangles have been synthesized from metallaligands. Enlargement of one linker leads to the isolation of two novel Borromean link architectures. All these complexes are intact in solution, as evident from ESI-MS spectroscopic analysis. Arising from the combination of open Cu centers and favorable cavity space, {(CpRh)4(bpe) 2[Cu(opba)·2MeOH]2}4(OTf)·6MeOH shows extraordinary catalytic abilities with high efficiency and wide substrate selectivity in the acyl-transfer reaction.

源语言英语
页(从-至)8125-8128
页数4
期刊Journal of the American Chemical Society
135
22
DOI
出版状态已出版 - 5 6月 2013
已对外发布

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Huang, S. L., Lin, Y. J., Hor, T. S. A., & Jin, G. X. (2013). Cp*Rh-based heterometallic metallarectangles: Size-dependent borromean link structures and catalytic acyl transfer. Journal of the American Chemical Society, 135(22), 8125-8128. https://doi.org/10.1021/ja402630g