Controllable synthesis of two adenosine 5′-monophosphate nucleotide coordination polymersviapH regulation: crystal structure and chirality

Wen Jing Song; Hao Su; Pei Zhou; Yan Hong Zhu; Maroof Ahmad Khan; Jian Biao Song; Hui Li

doi:10.1039/d1dt00133g

Controllable synthesis of two adenosine 5′-monophosphate nucleotide coordination polymersviapH regulation: crystal structure and chirality

Wen Jing Song, Hao Su, Pei Zhou, Yan Hong Zhu, Maroof Ahmad Khan, Jian Biao Song, Hui Li^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

Two types of Cu(ii)-AMP-4,4′-bipy coordination polymers, {[Cu(AMP)(4,4′-bipy)(H₂O)₃]·5H₂O}n(1) and {[Cu₂(HAMP)₂(4,4′-bipy)₂(H₂O)₄]·2NO₃·11H₂O}n (2) (Na₂AMP = adenosine 5′-monophosphate disodium salt), were synthesised through pH control. X-ray single-crystal diffraction analysis revealed that1and2are one-dimensional (1D) coordinating coordination polymers. The nucleotide in1was not protonated whereas that in2was protonated. With the protonated NO₃⁻in2entering the crystal lattice, it plays a role in balancing the charge. The chirality was studied using solid-state circular dichroism (CD) spectroscopy based on the analysis of crystal structures.

源语言	英语
页（从-至）	4713-4719
页数	7
期刊	Dalton Transactions
卷	50
期	13
DOI	https://doi.org/10.1039/d1dt00133g
出版状态	已出版 - 7 4月 2021

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10.1039/d1dt00133g

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title = "Controllable synthesis of two adenosine 5′-monophosphate nucleotide coordination polymersviapH regulation: crystal structure and chirality",

abstract = "Two types of Cu(ii)-AMP-4,4′-bipy coordination polymers, {[Cu(AMP)(4,4′-bipy)(H2O)3]·5H2O}n(1) and {[Cu2(HAMP)2(4,4′-bipy)2(H2O)4]·2NO3·11H2O}n (2) (Na2AMP = adenosine 5′-monophosphate disodium salt), were synthesised through pH control. X-ray single-crystal diffraction analysis revealed that1and2are one-dimensional (1D) coordinating coordination polymers. The nucleotide in1was not protonated whereas that in2was protonated. With the protonated NO3−in2entering the crystal lattice, it plays a role in balancing the charge. The chirality was studied using solid-state circular dichroism (CD) spectroscopy based on the analysis of crystal structures.",

author = "Song, {Wen Jing} and Hao Su and Pei Zhou and Zhu, {Yan Hong} and Khan, {Maroof Ahmad} and Song, {Jian Biao} and Hui Li",

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T1 - Controllable synthesis of two adenosine 5′-monophosphate nucleotide coordination polymersviapH regulation

T2 - crystal structure and chirality

AU - Song, Wen Jing

AU - Su, Hao

AU - Zhou, Pei

AU - Zhu, Yan Hong

AU - Khan, Maroof Ahmad

AU - Song, Jian Biao

AU - Li, Hui

PY - 2021/4/7

Y1 - 2021/4/7

N2 - Two types of Cu(ii)-AMP-4,4′-bipy coordination polymers, {[Cu(AMP)(4,4′-bipy)(H2O)3]·5H2O}n(1) and {[Cu2(HAMP)2(4,4′-bipy)2(H2O)4]·2NO3·11H2O}n (2) (Na2AMP = adenosine 5′-monophosphate disodium salt), were synthesised through pH control. X-ray single-crystal diffraction analysis revealed that1and2are one-dimensional (1D) coordinating coordination polymers. The nucleotide in1was not protonated whereas that in2was protonated. With the protonated NO3−in2entering the crystal lattice, it plays a role in balancing the charge. The chirality was studied using solid-state circular dichroism (CD) spectroscopy based on the analysis of crystal structures.

AB - Two types of Cu(ii)-AMP-4,4′-bipy coordination polymers, {[Cu(AMP)(4,4′-bipy)(H2O)3]·5H2O}n(1) and {[Cu2(HAMP)2(4,4′-bipy)2(H2O)4]·2NO3·11H2O}n (2) (Na2AMP = adenosine 5′-monophosphate disodium salt), were synthesised through pH control. X-ray single-crystal diffraction analysis revealed that1and2are one-dimensional (1D) coordinating coordination polymers. The nucleotide in1was not protonated whereas that in2was protonated. With the protonated NO3−in2entering the crystal lattice, it plays a role in balancing the charge. The chirality was studied using solid-state circular dichroism (CD) spectroscopy based on the analysis of crystal structures.

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Controllable synthesis of two adenosine 5′-monophosphate nucleotide coordination polymersviapH regulation: crystal structure and chirality

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