Comparison of crown ether side-chain polysiloxanes with and without liquid crystalline character as stationary phases for capillary gas chromatography

Wei Zhou, Ruonong Fu*, Rongji Dai, Zaifu Huang, Yanfei Chen

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摘要

Two new GC stationary phases were prepared, one a side-chain liquid crystalline polysiloxane containing crown ether (PSC-11), and the other a new kind of side-chain crown ether (PSCP-11-15C-5) which has a similar structure to PSC-11. The main chromatographic characteristics, including efficiency, polarity and selectivity, were examined and compared. The mechanism of specific selectivity for positional isomer compounds based on the crown ether ring and liquid crystal is discussed.

源语言英语
页(从-至)477-480
页数4
期刊Journal of Chromatography A
659
2
DOI
出版状态已出版 - 28 1月 1994

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Zhou, W., Fu, R., Dai, R., Huang, Z., & Chen, Y. (1994). Comparison of crown ether side-chain polysiloxanes with and without liquid crystalline character as stationary phases for capillary gas chromatography. Journal of Chromatography A, 659(2), 477-480. https://doi.org/10.1016/0021-9673(94)85090-9