Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air

Jupeng Chen, Xiaolin Wu, Shaowen Zhang*, Xiangqian Yan, Xiaolu Wu, Qingbin Cao, Huan Xu, Xiaofang Li*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

摘要

Commercially available palladium salts (1-4) (1: PdCl2; 2: PdCl2(CH3CN)2; 3: PdCl2(C6H5CN)2; and 4: Pd(OAc)2) served as low-cost, stable, green, broad-spectrum, and single-component catalysts with low sensitivity toward functional groups and solvents during the coordination polymerization of various 1-chloro-2-phenylacetylenes, Cl-C ≡ C-C6H4R (a-j), in air without a co-catalyst, providing a new metal catalyst design concept for the coordination polymerization of disubstituted alkynes.

源语言英语
页(从-至)3870-3875
页数6
期刊Polymer Chemistry
13
26
DOI
出版状态已出版 - 27 6月 2022

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