Cobalt(III)-catalyzed 1,4-addition of C-H bonds of oximes to maleimides

Xiangxiang Chen; Jiangtao Ren; Hu Xie; Wei Sun; Meng Sun; Biao Wu

doi:10.1039/c7qo00687j

Cobalt(III)-catalyzed 1,4-addition of C-H bonds of oximes to maleimides

Xiangxiang Chen, Jiangtao Ren, Hu Xie, Wei Sun, Meng Sun^*, Biao Wu

^*此作品的通讯作者

Northwest University China

科研成果: 期刊稿件 › 文章 › 同行评审

54 引用（Scopus）

摘要

Oxime directed cobalt-catalyzed arene sp² C-H bond conjugation addition to maleimide was reported, the reaction showed great tolerance to different functional groups, and various succinimide derivatives were efficiently produced. This protocol exhibited specific reactivity with only producing a mono-C-H bond addition product and no external base was needed, which suggested a unique reactivity of this Co-based catalytic system.

源语言	英语
页（从-至）	184-188
页数	5
期刊	Organic Chemistry Frontiers
卷	5
期	2
DOI	https://doi.org/10.1039/c7qo00687j
出版状态	已出版 - 21 1月 2018
已对外发布	是

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abstract = "Oxime directed cobalt-catalyzed arene sp2 C-H bond conjugation addition to maleimide was reported, the reaction showed great tolerance to different functional groups, and various succinimide derivatives were efficiently produced. This protocol exhibited specific reactivity with only producing a mono-C-H bond addition product and no external base was needed, which suggested a unique reactivity of this Co-based catalytic system.",

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AU - Chen, Xiangxiang

AU - Ren, Jiangtao

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AU - Sun, Wei

AU - Sun, Meng

AU - Wu, Biao

PY - 2018/1/21

Y1 - 2018/1/21

N2 - Oxime directed cobalt-catalyzed arene sp2 C-H bond conjugation addition to maleimide was reported, the reaction showed great tolerance to different functional groups, and various succinimide derivatives were efficiently produced. This protocol exhibited specific reactivity with only producing a mono-C-H bond addition product and no external base was needed, which suggested a unique reactivity of this Co-based catalytic system.

AB - Oxime directed cobalt-catalyzed arene sp2 C-H bond conjugation addition to maleimide was reported, the reaction showed great tolerance to different functional groups, and various succinimide derivatives were efficiently produced. This protocol exhibited specific reactivity with only producing a mono-C-H bond addition product and no external base was needed, which suggested a unique reactivity of this Co-based catalytic system.

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Cobalt(III)-catalyzed 1,4-addition of C-H bonds of oximes to maleimides

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