Charge State Tristability of Oxygen Adatom on a Rutile TiO2(110)-(1 × 1) Surface Controlled by Atomic Force Microscopy

Yuuki Adachi, Huan Fei Wen, Quanzhen Zhang, Masato Miyazaki, Yasuhiro Sugawara, Ján Brndiar, Lev Kantorovich, Ivan Štich, Yan Jun Li*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

4 引用 (Scopus)

摘要

We show that a single oxygen adatom on a rutile TiO2(110)-(1 × 1) surface is charge tristable, forming Oad2-, Oad-, and Oad0, and that the charge states can be controlled with single-electron precision using atomic force microscopy and Kelvin probe force spectroscopy. The experimental results show that Oad0is indeed the lowest redox state of the oxygen adatom and that Oad+is not achievable. Our findings expand our understanding of the chemical nature of the oxygen adatom on metal oxide surfaces.

源语言英语
页(从-至)5064-5069
页数6
期刊Journal of Physical Chemistry C
126
10
DOI
出版状态已出版 - 17 3月 2022
已对外发布

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