Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

Xiaofang Li; Masayoshi Nishiura; Kyouichi Mori; Tomohiro Mashiko; Zhaomin Hou

doi:10.1039/b708534f

Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

Xiaofang Li, Masayoshi Nishiura, Kyouichi Mori, Tomohiro Mashiko, Zhaomin Hou^*

^*此作品的通讯作者

RIKEN

科研成果: 期刊稿件 › 文章 › 同行评审

184 引用（Scopus）

摘要

A structurally well-defined THF-free cationic half-sandwich scandium aminobenzyl complex serves as a novel catalyst for the first copolymerization of 1-hexene with dicyclopentadiene to give the random copolymers with a wide range of 1-hexene contents (32-70 mol%) unavailable previously.

源语言	英语
页（从-至）	4137-4139
页数	3
期刊	Chemical Communications
期	40
DOI	https://doi.org/10.1039/b708534f
出版状态	已出版 - 2007
已对外发布	是

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abstract = "A structurally well-defined THF-free cationic half-sandwich scandium aminobenzyl complex serves as a novel catalyst for the first copolymerization of 1-hexene with dicyclopentadiene to give the random copolymers with a wide range of 1-hexene contents (32-70 mol%) unavailable previously.",

author = "Xiaofang Li and Masayoshi Nishiura and Kyouichi Mori and Tomohiro Mashiko and Zhaomin Hou",

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AU - Li, Xiaofang

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AU - Mashiko, Tomohiro

AU - Hou, Zhaomin

PY - 2007

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AB - A structurally well-defined THF-free cationic half-sandwich scandium aminobenzyl complex serves as a novel catalyst for the first copolymerization of 1-hexene with dicyclopentadiene to give the random copolymers with a wide range of 1-hexene contents (32-70 mol%) unavailable previously.

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SN - 1359-7345

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JO - Chemical Communications

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Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

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