摘要
The title compound, [Co(C2N3)(NO3)(C14H12N2)] n , exhibits a zigzag chain structure. The CoII atom has a slightly distorted octa-hedral geometry formed by two N atoms of a 2,9-dimethyl-1,10-phenanthroline ligand, two N atoms from two different dicyanamide ligands and two O atoms of a nitrate anion. A one-dimensional chain is formed through the dicyanamides, which act as end-to-end bridging ligands. The chains are linked into a three-dimensional network via weak C - H⋯O hydrogen bonds.
源语言 | 英语 |
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页(从-至) | m1986 |
期刊 | Acta Crystallographica Section E: Structure Reports Online |
卷 | 63 |
期 | 7 |
DOI | |
出版状态 | 已出版 - 6 6月 2007 |
指纹
探究 'Catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-k2 N,N′)(nitrato-k2 O,O′)cobalt(II)]-μ-dicyanamido-k 2 N 1:N 5]' 的科研主题。它们共同构成独一无二的指纹。引用此
Wang, Y. Y., & Liu, T. F. (2007). Catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-k2 N,N′)(nitrato-k2 O,O′)cobalt(II)]-μ-dicyanamido-k 2 N 1:N 5]. Acta Crystallographica Section E: Structure Reports Online, 63(7), m1986. https://doi.org/10.1107/S1600536807030279