C-N键联唑类高氮含能化合物1-(1H-1,2,4-三唑-3-基)-1H-四唑金属盐的合成与性能

Le Wu; Piao He; Hao Zheng Mei; Jian Guo Zhang

doi:10.11943/CJEM2018239

C-N键联唑类高氮含能化合物1-(1H-1,2,4-三唑-3-基)-1H-四唑金属盐的合成与性能

Le Wu, Piao He, Hao Zheng Mei, Jian Guo Zhang^*

^*此作品的通讯作者

机电学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

Seven metal salts based on the 1-(1H-1,2,4-triazole-3-yl)-1H-tetrazole were synthesized firstly by using the reaction with related hydroxide or carbonate. They are characterized by using EA, IR, NMR technologies. And X-ray single crystals of five metal salts were obtained. The thermal stability of the metal salts was studied by DSC. Most of them have good thermal stability after the water molecular was lost, and the decomposition temperature of lithium salts is highest with a value of 258 ℃. The enthalpy of formation was calculated by the isometric reaction method. The enthalpy of formation of two metal salts are higher than 1000 kJ•mol^-1. The detonation performance was estimated by using EXPLO5 software, and the impact sensitivity and friction sensitivity were tested. The results show that these metal salt are insensitive energetic materials.

投稿的翻译标题	Synthesis and Properties of C-N linked Azole-based High-Nitrogen Energetic Compound:Metal Salts Based on the 1-(1H-1,2,4-Triazole-3-yl)-1H-tetrazole
源语言	繁体中文
页（从-至）	951-957
页数	7
期刊	Hanneng Cailiao/Chinese Journal of Energetic Materials
卷	26
期	11
DOI	https://doi.org/10.11943/CJEM2018239
出版状态	已出版 - 25 11月 2018

关键词

1-(1H-1,2,4-triazole-3-yl)-1H-tetrazole
Crystal structure
Detonation performance
Metal salts
Thermal stability

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10.11943/CJEM2018239

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abstract = "Seven metal salts based on the 1-(1H-1,2,4-triazole-3-yl)-1H-tetrazole were synthesized firstly by using the reaction with related hydroxide or carbonate. They are characterized by using EA, IR, NMR technologies. And X-ray single crystals of five metal salts were obtained. The thermal stability of the metal salts was studied by DSC. Most of them have good thermal stability after the water molecular was lost, and the decomposition temperature of lithium salts is highest with a value of 258 ℃. The enthalpy of formation was calculated by the isometric reaction method. The enthalpy of formation of two metal salts are higher than 1000 kJ•mol-1. The detonation performance was estimated by using EXPLO5 software, and the impact sensitivity and friction sensitivity were tested. The results show that these metal salt are insensitive energetic materials.",

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author = "Le Wu and Piao He and Mei, {Hao Zheng} and Zhang, {Jian Guo}",

year = "2018",

month = nov,

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doi = "10.11943/CJEM2018239",

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T1 - C-N键联唑类高氮含能化合物1-(1H-1,2,4-三唑-3-基)-1H-四唑金属盐的合成与性能

AU - Wu, Le

AU - He, Piao

AU - Mei, Hao Zheng

AU - Zhang, Jian Guo

PY - 2018/11/25

Y1 - 2018/11/25

N2 - Seven metal salts based on the 1-(1H-1,2,4-triazole-3-yl)-1H-tetrazole were synthesized firstly by using the reaction with related hydroxide or carbonate. They are characterized by using EA, IR, NMR technologies. And X-ray single crystals of five metal salts were obtained. The thermal stability of the metal salts was studied by DSC. Most of them have good thermal stability after the water molecular was lost, and the decomposition temperature of lithium salts is highest with a value of 258 ℃. The enthalpy of formation was calculated by the isometric reaction method. The enthalpy of formation of two metal salts are higher than 1000 kJ•mol-1. The detonation performance was estimated by using EXPLO5 software, and the impact sensitivity and friction sensitivity were tested. The results show that these metal salt are insensitive energetic materials.

AB - Seven metal salts based on the 1-(1H-1,2,4-triazole-3-yl)-1H-tetrazole were synthesized firstly by using the reaction with related hydroxide or carbonate. They are characterized by using EA, IR, NMR technologies. And X-ray single crystals of five metal salts were obtained. The thermal stability of the metal salts was studied by DSC. Most of them have good thermal stability after the water molecular was lost, and the decomposition temperature of lithium salts is highest with a value of 258 ℃. The enthalpy of formation was calculated by the isometric reaction method. The enthalpy of formation of two metal salts are higher than 1000 kJ•mol-1. The detonation performance was estimated by using EXPLO5 software, and the impact sensitivity and friction sensitivity were tested. The results show that these metal salt are insensitive energetic materials.

KW - 1-(1H-1,2,4-triazole-3-yl)-1H-tetrazole

KW - Crystal structure

KW - Detonation performance

KW - Metal salts

KW - Thermal stability

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M3 - 文章

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JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

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ER -

C-N键联唑类高氮含能化合物1-(1H-1,2,4-三唑-3-基)-1H-四唑金属盐的合成与性能

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