Budding willow branches shaped Na3V2(PO4)3/C nanofibers synthesized via an electrospinning technique and used as cathode material for sodium ion batteries

Hui Li, Ying Bai*, Feng Wu, Yu Li, Chuan Wu

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

143 引用 (Scopus)

摘要

Budding willow branches shaped Na3V2(PO4)3/C nanofibers were successfully synthesized by a simple electrospinning technique with Poly(vinyl pyrrilidone) (PVP). The Na3V2(PO4)3/C nanoparticles that anchored on the nanofibers surface seemed like the willow buds; the inner core of the nanofibers, which composed Na3V2(PO4)3, looked like willow twig and the uniform carbon layer was same with willow bark. Such special morphology played a vital role in improving cycle stability and rate capability of the electrode due to the conductive network built up by nanofibers. The Na3V2(PO4)3/C nanofibers cathode exhibited an initial specific capacity of 106.8 mAh g-1 at a current density of 0.2C, still stabling at 107.2 mAh g-1 after 125 cycles with excellent cycle stability. Moreover, a capacity retention of 95.7% was obtained when Na3V2(PO4)3/C nanofibers cycled stepwise from 0.2 to 2C. Good electrochemical performance should be ascribed to both the special morphology and preferential growth of the (113) plane. The simple synthesis technique and good electrochemical performance suggests that this material with the special shape of budding willow branches is a promising cathode for sodium ion batteries.

源语言英语
页(从-至)784-792
页数9
期刊Journal of Power Sources
273
DOI
出版状态已出版 - 1 1月 2015

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